923494
iPrMPhos
powder or chunks
Synonym(s):
1-Diadamantylphosphino-1′-diisopropylphosphinoferrocene
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About This Item
Empirical Formula (Hill Notation):
C36H52FeP2
Molecular Weight:
602.59
UNSPSC Code:
12352128
NACRES:
NA.21
Form:
powder or chunks
Product Name
iPrMPhos,
form
powder or chunks
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligand
mp
172-175 °C
functional group
phosphine
Application
iPrMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing iPrMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).
Learn more about MPhos ligands and catalysts
Learn more about MPhos ligands and catalysts
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Articles
YPhos ligands facilitate palladium-catalyzed coupling reactions of aryl chlorides under mild conditions with short reaction times.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 923494-500MG | 04065267054148 |
| 923494-100MG | 04065267054131 |