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ALD00600

Zhu-Yu Auxiliary

Name: Zhu-Yu Auxiliary
Brand: ALDRICH

98%

Synonym(s):

1-Carboxy-1-methylethoxyammonium chloride, 2,2-Dimethyl aminooxyacetic, 2-(Aminooxy)-2-methylpropanoic acid hydrochloride

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About This Item

Empirical Formula (Hill Notation):

C₄H₁₀ClNO₃

CAS Number:

89766-91-6

Molecular Weight:

155.58

UNSPSC Code:

12352101

MDL number:

MFCD08063911

NACRES:

NA.22

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Properties

assay

98%

form

powder or crystals

reaction suitability

reaction type: C-C Bond Formation, reagent type: catalyst, reagent type: ligand
reaction type: C-H Activation

availability

available only in USA

mp

150-165 °C

SMILES string

[Cl-].NOC(C)(C)C(=O)O.[H+]

InChI

1S/C4H9NO3.ClH/c1-4(2,8-5)3(6)7;/h5H2,1-2H3,(H,6,7);1H

InChI key

ZJPZGAAOCIFBDI-UHFFFAOYSA-N

Description

Application

The Zhu-Yu Auxiliary was reported by Jin-Quan Yu′s lab to be an effective auxiliary for the Pd(II)-catalyzed β-C(sp3)-H(hetero)arylation of ketones.

Other Notes

Versatile Alkylation of (Hetero)Aryl Iodides with Ketones via β-C(sp3)-H Activation

pictograms

GHS02

signalword

Danger

hcodes

H242

pcodes

P210 - P234 - P235 - P240 - P370 + P378 - P403

Hazard Classifications

Self-react. C

Storage Class

5.2 - Organic peroxides and self-reacting hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Global Trade Item Number

SKU	GTIN
ALD00600-5G	04061835511198
ALD00600-1G	04061835511174