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About This Item
NACRES:
NA.22
UNSPSC Code:
41116155
storage temp.
2-8°C
Application
The Baran Late-Stage Toolkit is a convenient collection of 12 highly innovative reagents that are highly effective in the diversification of complex molecules. The contents in the box are 11 Baran Diversinates™ and one vial of Palau′Chlor® in amounts of 100 mg each. For obtaining larger amounts of any desired kit component, see the kit component table at the bottom of the page.
Useful Topics:
Late Stage Functionalization
Baran Group – Professor Product Portal
Palau′Chlor
Diversinates
Useful Topics:
Late Stage Functionalization
Baran Group – Professor Product Portal
Palau′Chlor
Diversinates
Legal Information
Diversinates is a trademark of Sigma-Aldrich Co. LLC
Palau′Chlor is a registered trademark of Merck KGaA, Darmstadt, Germany
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Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
8A - Combustible corrosive hazardous materials
Regulatory Information
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A C?H Methylation Reaction of Heteroarenes Inspired by Radical SAM Methyl Transferase.
Gui J, et al.
Journal of the American Chemical Society, 136, 4853-4856 (2014)
Palau'chlor: A Practical and Reactive Chlorinating Reagent
Rodriguez RA, et al.
Journal of the American Chemical Society, 136, 6908-6911 (2014)
Radical C?H Functionalization of Heteroarenes under Electrochemical Control.
O'Brien, et al.
Angewandte Chemie (International Edition in English), 53, 11868-11871 (2014)
Simple Sulfinate Synthesis Enables C-H Trifluoromethylcyclopropanation
Gianatassio R, et al.
Angewandte Chemie (International Edition in English), 53, 9851-9855 (2014)
Yuta Fujiwara et al.
Journal of the American Chemical Society, 134(3), 1494-1497 (2012-01-11)
Molecular scaffolds containing alkylfluorine substituents are desired in many areas of chemical research from materials to pharmaceuticals. Herein, we report the invention of a new reagent (Zn(SO(2)CF(2)H)(2), DFMS) for the innate difluoromethylation of organic substrates via a radical process. This
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Baran Group offers zinc-based reagents for versatile transformations in organic synthesis.
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