33092-U
tert-Butyldimethylsilylimidazole solution
TBDMSIM in DMF, pkg of 10 × 1 mL
Synonym(s):
1-(tert-Butyldimethylsilyl)imidazole solution
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About This Item
Empirical Formula (Hill Notation):
C9H18N2Si
CAS Number:
Molecular Weight:
182.34
UNSPSC Code:
12352200
description
Silylation reagent
Quality Level
packaging
pkg of 10 × 1 mL
concentration
TBDMSIM in DMF
InChI
1S/C9H18N2Si/c1-9(2,3)12(4,5)11-7-6-10-8-11/h6-8H,1-5H3
InChI key
VUENSYJCBOSTCS-UHFFFAOYSA-N
General description
tert-Butyldimethylsilylimidazole solution is a derivatizing reagent. It is most effective for silylating multiwall carbon nanotubes (MWNT).
Application
It was used to convert oxysterols to tert-butyldimethylsilyl (TBDMSi) ethers for 18O enrichment during oxysterols determination in plasma and liver, using gas/liquid chromatography-mass spectrometry analysis.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Corr. 1A
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
71.6 °F - closed cup
flash_point_c
22 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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O Breuer et al.
The Journal of biological chemistry, 270(35), 20278-20284 (1995-09-01)
Cholesterol oxidation products (oxysterols) have been detected in many different tissues, often at concentrations 10(3) to 10(4) times lower than cholesterol. This constitutes a considerable risk of quantitation errors, since even a minor oxidation of cholesterol during sample processing would
E.J.Corey and A. Venkateswarlu
Journal of the American Chemical Society, 94, 6190-6190 (1972)
Yury Gogotsi
Nanotubes and Nanofibers, 46-46 (2006)