155683
3-氨基甲酰-2,2,5,5-四甲基-3-吡咯啉-1-氧基
99%
别名:
2,2,5,5-Tetramethyl-3-carbamido-3-pyrroline-1-oxyl, 3-氨基甲酰-2,5-二氢-2,2,5,5-四甲基-1H-吡咯-1-基氧基
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关于此项目
经验公式（希尔记法）:
C9H15N2O2
化学文摘社编号:
分子量:
183.23
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-765-9
Beilstein/REAXYS Number:
4138020
MDL number:
产品名称
3-氨基甲酰-2,2,5,5-四甲基-3-吡咯啉-1-氧基, 99%
InChI key
RUEXQFPLRRIFTI-UHFFFAOYSA-N
InChI
1S/C9H15N2O2/c1-8(2)5-6(7(10)12)9(3,4)11(8)13/h5H,1-4H3,(H2,10,12)
SMILES string
CC1(C)C=C(C(N)=O)C(C)(C)N1[O]
assay
99%
form
solid
mp
197-200 °C (lit.)
functional group
amide
storage temp.
2-8°C
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Application
自旋标记物
3-Carbamoyl-2,2,5,5-tetramethyl-3-pyrrolin-1-oxyl is a nitroxide radical that can be used:
- As a spin probe in the study of simulation of Overhauser dynamic nuclear polarization signal.
- As a starting material in the synthesis of nitroxide based polyethers possessing charge transport properties.
- As a nitroxide imaging probe applicable for EPR imaging of brain diseases in animal models.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Ichiro Koshiishi et al.
The Biochemical journal, 395(2), 303-309 (2006-01-07)
Lipoxygenases have been proposed to be a possible factor that is responsible for the pathology of certain diseases, including ischaemic injury. In the peroxidation process of linoleic acid by lipoxygenase, the E,Z-linoleate allyl radical-lipoxygenase complex seems to be generated as
F Gomi et al.
Life sciences, 52(25), 2027-2033 (1993-01-01)
After the nitroxyl radical 3-carbamoyl-2,2,5,5-tetramethyl-1-pyrrolidinyloxyl (carbamoylPROXYL) was intraperitoneally administered to mice, the time courses of changes in the intensity of signals in L-band electron spin resonance spectra from their brains were measured. The spin clearance rate of old, ad libitum-fed
B H Robinson et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 138(2), 210-219 (1999-05-26)
This work demonstrates that homogeneous linewidths can be extracted from continuous wave electron paramagnetic resonance spectra and that they quantitatively agree with the predictions of existing relaxation theory. We suggest that relaxation theory can be used to predict experimental lineshapes
Hiroshi Hirata et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 190(1), 124-134 (2007-11-17)
A loop resonator was developed for 300 MHz continuous-wave electron paramagnetic resonance (CW-EPR) spectroscopy and imaging in live rats. A single-turn loop (55 mm in diameter) was used to provide sufficient space for the rat body. Efficiency for generating a
Synthesis and charge transport properties of redox-active nitroxide polyethers with large site density
Oyaizu K, et al.
Macromolecules, 43(24), 10382-10389 (2010)
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