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Merck
CN

180858

二溴化-1,1ˊ-二庚基-4,4ˊ-联吡啶鎓

97%

别名:

N ,N ′-Diheptyl-4,4′-dipyridylium dibromide, DHPB, Diheptylviologen bromide, Diheptylviologen dibromide, Heptylviologen dibromide

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关于此项目

经验公式(希尔记法):
C24H38Br2N2
化学文摘社编号:
分子量:
514.38
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
228-178-7
MDL number:
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InChI key

VRXAJMCFEOESJO-UHFFFAOYSA-L

InChI

1S/C24H38N2.2BrH/c1-3-5-7-9-11-17-25-19-13-23(14-20-25)24-15-21-26(22-16-24)18-12-10-8-6-4-2;;/h13-16,19-22H,3-12,17-18H2,1-2H3;2*1H/q+2;;/p-2

SMILES string

[Br-].[Br-].CCCCCCC[n+]1ccc(cc1)-c2cc[n+](CCCCCCC)cc2

assay

97%

form

crystals

mp

285 °C (dec.) (lit.)

Application

DHBP is an EC material which can be used in the fabrication of electronic devices such as organic light emitting diodes (OLED), supercapacitors, and liquid crystal displays (LCDs).

General description

1,1′-Diheptyl-4,4′-bipyridinium dibromide (DHBP) is a heptyl viologen that can be used as an electrochromic (EC) material. It forms a highly efficient quenching system for conjugated polyelectrolyte for the development of organic electronics. It also acts as a redox active electrolyte for electrochemical devices (ECDs).

pictograms

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signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Achieving low-energy driven viologens-based electrochromic devices utilizing polymeric ionic liquids.
Lu H, et al.
ACS Applied Materials & Interfaces, 8(44), 30351-30361 (2016)
Efficient charge storage in dual-redox electrochemical capacitors through reversible counterion-induced solid complexation.
Evanko B, et al.
Journal of the American Chemical Society, 138(30), 9373-9376 (2016)
Electrochemically controllable emission and coloration by using europium (III) complex and viologen derivatives.
Nakamura K, et al.
Chemical Communications (Cambridge, England), 47(36), 10064-10066 (2011)
The effect of ferrocyanide on the performance of heptyl viologen-based electrochromic display devices.
Monk PMS.
Journal of Electroanalytical Chemistry, 432(1-2), 175-179 (1997)
Ink-Jet Printing of Electron Donor/Acceptor Blends: Towards Bulk Heterojunction Solar Cells
Marin, V., Holder, E., Wienk, M. M., Tekin, E., Kozodaev, D., & Schubert, U. S.
Macromolecular Rapid Communications, 26(4), 319-324 (2005)

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