237752
-吡哌酸
Proline homolog., 99%
别名:
-高脯氨酸, （S）-（& # 8722;）-2-哌啶羧酸
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关于此项目
经验公式（希尔记法）:
C6H11NO2
化学文摘社编号:
分子量:
129.16
EC Number:
221-462-1
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
81093
MDL number:
产品名称
-吡哌酸, Proline homolog., 99%
InChI key
HXEACLLIILLPRG-YFKPBYRVSA-N
InChI
1S/C6H11NO2/c8-6(9)5-3-1-2-4-7-5/h5,7H,1-4H2,(H,8,9)/t5-/m0/s1
SMILES string
OC(=O)[C@@H]1CCCCN1
assay
99%
form
powder with small lumps
optical activity
[α]25/D −26.4°, c = 1 in H2O
color
white
mp
272 °C (lit.)
application(s)
peptide synthesis
storage temp.
2-8°C
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General description
Occurs in seeds, malt, edible mushrooms, fruits, etc.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
S J Mihalik et al.
Pediatric research, 25(5), 548-552 (1989-05-01)
L-Pipecolic acid, a cyclic imino acid produced during the degradation of lysine, accumulates in body fluids of infants with the generalized peroxisomal disorders, including Zellweger syndrome, neonatal adrenoleukodystrophy, and infantile Refsum disease. Peroxisome-enriched fractions from normal human liver oxidized L-[3H]pipecolic
D W Armstrong et al.
Journal of pharmaceutical and biomedical analysis, 11(10), 881-886 (1993-10-01)
Recently it was found that normal adults excrete pipecolic acid primarily as the D-enantiomer even though it is present in the blood stream mainly as the L-enantiomer (i.e. > 98% L). This study of pipecolic acid stereochemistry was extended to
Arjun Sengupta et al.
Malaria journal, 10, 384-384 (2011-12-27)
Plasmodium vivax is responsible for the majority of malarial infection in the Indian subcontinent. This species of the parasite is generally believed to cause a relatively benign form of the disease. However, recent reports from different parts of the world
Susan Keay et al.
Chemical biology & drug design, 77(6), 421-430 (2011-03-01)
Interstitial cystitis/painful bladder syndrome is a chronic bladder disorder with epithelial thinning or ulceration, pain, urinary frequency and urgency, for which there is no reliably effective therapy. We previously reported that interstitial cystitis/painful bladder syndrome bladder epithelial cells make a
Kuo-Yuan Hung et al.
The Journal of organic chemistry, 75(24), 8728-8731 (2010-11-26)
An efficient stereoselective synthesis of fully protected (2S,4R)-4-methylpipecolic acid has been developed. The synthesis was achieved by initial asymmetric α-alkylation of glycine with a chiral iodide, affording the linear precursor as a single stereoisomer. Subsequent aldehyde formation using OsO(4)/NaIO(4) followed
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