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331880

(1S,2R)-(+)-2-氨基-1,2-二苯基乙醇

Name: (1<I>S</I>,2<I>R</I>)-(+)-2-氨基-1,2-二苯基乙醇
Brand: ALDRICH

99%

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关于此项目

线性分子式:

C₆H₅CH(NH₂)CH(C₆H₅)OH

化学文摘社编号:

23364-44-5

分子量:

213.28

UNSPSC Code:

12352116

NACRES:

NA.22

PubChem Substance ID:

24860005

MDL number:

MFCD00074959

Beilstein/REAXYS Number:

1212828

Assay:

99%

Form:

solid

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属性

Quality Level

100

assay

99%

form

solid

optical activity

[α]25/D +7.0°, c = 0.6 in ethanol

mp

142-144 °C (lit.)

functional group

amine, hydroxyl, phenyl

SMILES string

N[C@@H]([C@@H](O)c1ccccc1)c2ccccc2

InChI

1S/C14H15NO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14,16H,15H2/t13-,14+/m1/s1

InChI key

GEJJWYZZKKKSEV-KGLIPLIRSA-N

说明

Application

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol can be used:

To prepare vanadium(V) Schiff base complexes, which are used as catalysts in the oxidation of sulfides and olefins.
To prepare chiral selectors, which are immobilized on aminated silica gel, applicable as chiral stationary phase in HPLC.
To immobilize on the frame of α-zirconium phosphate to yield layered zirconium phosphonates, which are used in the heterogeneous catalysis.
As a chiral auxiliary in the preparation of homopropargylic alcohols from aliphatic and aromatic aldehydes.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Zirconium phosphonate immobilized chiral amino alcohol for heterogeneous enantioselective addition of diethylzinc to benzaldehyde

Zheng B, et al.

Catalysis Communications, 8(12), 1923-1928 (2007)

Vanadium (V) complexes with chiral tridentate Schiff base ligands derived from 1S, 2R (+)-2-amino-1, 2-diphenylethanol and with acetohydroxamate co-ligand: Synthesis, characterization and catalytic activity in the oxidation of prochiral sulfides and olefins

Romanowski G, et al.

J. Mol. Catal. A: Chem., 381, 148-160 (2014)

Asymmetric indium-mediated synthesis of homopropargylic alcohols

Hirayama LC, et al.

Tetrahedron Letters, 47(29), 5173-5176 (2006)

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全球贸易项目编号

货号	GTIN
331880-1G	04061826249147
331880-5G	04061833037942