369500
4,4′-亚甲基双(2-甲基环己胺)，异构体混合物
99%
别名:
2,2′-二甲基-4,4′-亚甲基双（环己胺）, 3,3′-二甲基-4,4′-二氨基二环己基甲烷, 4,4′-二氨基-3,3′-二甲基二环己基甲烷, DMDC, 双(3-甲基-4-氨基环己基)甲烷
质量水平
方案
99%
表单
liquid
折射率
n20/D 1.499 (lit.)
沸点
93-100 °C (lit.)
密度
0.94 g/mL at 25 °C (lit.)
SMILES字符串
CC1CC(CCC1N)CC2CCC(N)C(C)C2
InChI
1S/C15H30N2/c1-10-7-12(3-5-14(10)16)9-13-4-6-15(17)11(2)8-13/h10-15H,3-9,16-17H2,1-2H3
InChI key
IGSBHTZEJMPDSZ-UHFFFAOYSA-N
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一般描述
4,4′-亚甲基双（2-甲基环己胺）是脂环二胺。
应用
4,4′-可使用亚甲基双（2-甲基环己基胺）(MMCA)：
- 全脂肪族聚酰亚胺的合成
- 在全脂肪族聚酰亚胺-硅氧烷 (APISiO) 的合成中
- 用三羟甲基丙烷三缩水甘油醚制备环氧树脂，用透射 X 射线显微术 (STXM) 表征拖丝的结构组织。
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Corr. 1A
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
343.4 °F - closed cup
闪点(°C)
173 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
S Ohshima et al.
The Journal of toxicological sciences, 11(2), 79-93 (1986-05-01)
Amine-curing agent for epoxy resin, bis(4-amino-3-methyl-cyclohexyl)methane (commercial name; Laromin C) has been suspected to have induced in the workers some toxic signs such as collagen disease like scleroderma or polymyositis. Subacute toxicity of this agent was studied in rats following
U F Haustein et al.
Dermatosen in Beruf und Umwelt. Occupation and environment, 34(3), 61-67 (1986-05-01)
For the stimulation of research on scleroderma and the prophylaxis of occupational scleroderma-like diseases and the prevention of iatrogenic injuries, respect., it is important to know the inducing environmental substances. Plastics (vinyl chloride, epoxy resins), solvents (chlorinated, aromatic and aliphatic
Synthesis and characterization of novel fully aliphatic polyimidosiloxanes based on alicyclic or adamantyl diamines.
Mathews AS, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 44(18), 5254-5270 (2006)
Fully aliphatic polyimides from adamantane-based diamines for enhanced thermal stability, solubility, transparency, and low dielectric constant.
Mathews AS, et al.
Journal of Applied Polymer Science, 102(4), 3316-3326 (2006)
S Ohshima et al.
Journal of toxicology and environmental health, 28(2), 249-255 (1989-01-01)
Repeated oral administration of bis(4-amino-3-methylcyclohexyl)methane to rats induced unusual ultrastructural changes in Clara cells of the bronchiolar epithelium, involving marked accumulation of electron-dense inclusion bodies with a lamellar structure in the cytoplasm. The appearance of the inclusion bodies was speculated
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