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Merck
CN
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About This Item

经验公式(希尔记法):
LiNi0.5Mn0.3Co0.2O2
CAS Number:
分子量:
96.55
UNSPSC代码:
26111700
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等级

battery grade

质量水平

描述

application(s): battery manufacturing

方案

99% trace metals basis

表单

powder

分子量

96.56 g/mol

组成

LiNi0.5Mn0.3Co0.2O2

密度

4.77 g/cm3 ((lit.))

SMILES字符串

[Li].[O].[Mn].[Co].[Ni]

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一般描述

Lithium niobate coated NMC532 is a powdered form of lithium nickel manganese cobalt oxide with a stoichiometry of 5:3:2 Ni:Mn:Co and a typical particle size of 4-10 microns. The particles are coated in 5-10 nm amorphous lithium niobate, less than 1 wt.%.

应用

LiNbO3-coated NMC532 is a high-performance cathode active material designed to be used in lithium-ion batteries (LIBs), particularly solid-state batteries and high-voltage LIBs. NMC532 balances the high capacity bestowed by 50% nickel with the structural stability imparted by the manganese and cobalt. Compared to NMC811, NMC532 tends to achieve better cycling lifetime and coulombic efficiencies. The LiNbO3-coating boosts the stability of the cathode material by protecting the electrode and electrolyte from unwanted reactions. Research indicates that the lithium-niobate coating, increases the capacity over time (less capacity fade) by mitigating reactions between the electrolyte and cathode material and by impeding the release of metal ions from the NMC cathode into the electrolyte. Additionally, the lithium-niobate coating, sometimes called a LiNbO3 insertion layer, improves the rate capability by reducing the space charge layer barrier at the electrolyte/cathode interface. This improvement is evidenced both in enhanced Li diffusion and smaller electrode polarization.

特点和优势

-NMC532 balances high capacity and long cycle lifetimes
-LiNbO3 coating protects the cathode and electrolyte, improving coulombic efficiency
-LiNbO3 insertion layer improves rate capability

象形图

Health hazardExclamation mark

警示用语:

Warning

危险声明

危险分类

Carc. 2 - Skin Sens. 1

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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