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Merck
CN

B65586

2-溴乙醇

95%

别名:

乙烯溴醇

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关于此项目

线性分子式:
BrCH2CH2OH
化学文摘社编号:
分子量:
124.96
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-748-1
Beilstein/REAXYS Number:
878140
MDL number:
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产品名称

2-溴乙醇, 95%

InChI key

LDLCZOVUSADOIV-UHFFFAOYSA-N

InChI

1S/C2H5BrO/c3-1-2-4/h4H,1-2H2

SMILES string

OCCBr

vapor density

4.3 (vs air)

vapor pressure

2.4 mmHg ( 20 °C)

assay

95%

form

liquid

refractive index

n20/D 1.492 (lit.)

bp

56-57 °C/20 mmHg (lit.)

density

1.763 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

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Application

2-溴乙醇可用于由乙酰化糖制备 2-溴乙基糖苷。它也可以用作合成 2-溴乙基甲氧基甲基醚的原料。
2-溴乙醇用于选择性还原硝基芳烃(PcFe(II)/NaBH4/2-溴乙醇催化剂体系)。

pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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2-Bromoethyl glycosides: synthesis and characterisation.
Dahmen J, et al.
Carbohydrate Research, 116(2), 303-307 (1983)
Regio?and Stereoselective Intramolecular Hydrosilylation of α?Hydroxy Enol Ethers: 2, 3?syn?2?Methoxymethoxy?1, 3?Nonanediol: 1, 3?Nonanediol, 2?(methoxymethoxy)?,(R, R)?(?)?.
Tamao K, et al.
Organic Syntheses, 73, 94-94 (2003)
J Fowles et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 39(11), 1055-1062 (2001-08-31)
Quantitative estimates of cancer risks from ethylene oxide (ETO) residues were constructed based on 200 retail samples of various spices in New Zealand. Two samples of cinnamon contained detectable ETO. The highest value encountered was 15 ppm. ETO was not
J R Van der Ploeg et al.
Archives of microbiology, 165(4), 258-264 (1996-04-01)
Pseudomonas sp. GJ1 is able to grow with 2-chloroethanol as the sole carbon and energy source, but not with 2-bromoethanol, which is toxic at low concentrations (1 mM). A mutant that could grow on 2-bromoethanol with a growth rate of
B S Kaphalia et al.
Journal of biochemical toxicology, 4(3), 183-188 (1989-01-01)
To study the formation of fatty acid conjugates of 2-chloroethanol (2-CE) and 2-bromoethanol (2-BE), rats were administered (by gavage) 50 mg/kg of 2-CE and 2-BE in mineral oil and sacrificed on fifth day of the treatment. Hepatic microsomal lipids were

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