方案
98%
表单
crystals
沸点
153 °C/23 mmHg (lit.)
mp
42-44 °C (lit.)
SMILES字符串
[O-][N+](=O)c1ccccc1C=O
InChI
1S/C7H5NO3/c9-5-6-3-1-2-4-7(6)8(10)11/h1-5H
InChI key
CMWKITSNTDAEDT-UHFFFAOYSA-N
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一般描述
2-硝基苯甲醛中的2-硝基苄基具有光不稳定性,当暴露于紫外光时会发生裂解。
应用
2-硝基苯甲醛可与壳聚糖反应形成2-硝基苄基-壳聚糖,其可溶于三氟乙酸,也可电纺成纳米纤维基质。在光解时,硝基苄基被裂解,以获得纯的壳聚糖纳米纤维基质。相同的原理已被应用于明胶纳米纤维基质的制备。o-NBA与2-氨基苯并噻唑的缩合反应可形成 o-硝基亚苄基-2-氨基苯并噻唑,其是一种Schiff碱,可与金属离子反应形成络合物。
警示用语:
Warning
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 2
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Studies on some Schiff base complexes of CoII, NiII and CuII derived from salicylaldehyde and o-nitrobenzaldehyde.
Zaki Z M, et al.
Spectroscopy Letters, 31(4), 757-766 (1998)
A smart methodology to fabricate electrospun chitosan nanofiber matrices for regenerative engineering applications.
Nada A A, et al.
Polymers For Advanced Technologies, 25(5), 507-515 (2014)
Two-photon photolysis of 2-nitrobenzaldehyde monitored by fluorescent-labeled nanocapsules.
Diaspro A, et al.
The Journal of Physical Chemistry B, 107(40), 11008-11012 (2003)
Gelatin nanofiber matrices derived from schiff base derivative for tissue engineering applications.
Jaiswal D, et al.
Journal of Biomedical Nanotechnology, 11(11), 2067-2080 (2015)
Annapaola Migani et al.
Chemical communications (Cambridge, England), 47(22), 6383-6385 (2011-05-10)
o-Nitrobenzaldehyde is photolabile because of an irreversible phototautomerization, whereas comparable aromatic compounds function as photoprotectors because the tautomerization is reversible. In this experimental and theoretical study we track down the cause of this difference to the electronic changes that occur
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