等级
synthesis grade
质量水平
蒸汽压
20 hPa ( 20 °C)
表单
liquid
效能
1136 mg/kg LD50, oral (Rat)
pH值（酸碱度）
12-13 (20 °C in H2O)
沸点
≥100 °C/1013 hPa
mp
<-3 °C
密度
1.20-1.25 g/cm3 at 20 °C
储存温度
2-30°C
应用
Sodium chlorite (NaClO2) can be used as an oxidizing agent for the conversion of:
It can also be used in combination with Br2 to synthesize 2-carboxyazetidin-2-ones from furanylazetidinones.
- Aldehydes to corresponding carboxylic acids under mild reaction conditions in the presence of scavengers such as sulfamic acid or resorcinol.
- Primary alcohols to carboxylic acids in the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and NaOCl.
- Aliphatic and aromatic thiols to the corresponding disulfides.
- Aryl boronic acids to phenols via ipso-hydroxylation.
- Cyclic benzylic ethers and N-protected cyclic benzylic amines to benzolactones and benzolactams.
- Alkenes to epoxides using aldehydes as promoters.
- Alkenes and cycloalkenes to 1, 2 diols via osmium-catalyzed Sharpless asymmetric dihydroxylation.
It can also be used in combination with Br2 to synthesize 2-carboxyazetidin-2-ones from furanylazetidinones.
分析说明
Assay (iodometric): 23.0 - 26.0 %
Density (d 20 °C/ 4 °C): 1.200 - 1.220
Density (d 20 °C/ 4 °C): 1.200 - 1.220
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1 - STOT RE 2
靶器官
spleen
补充剂危害
储存分类代码
6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
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