vapor pressure
233 hPa ( 20 °C)
Quality Segment
form
liquid
reaction suitability
reagent type: oxidant
kinematic viscosity
0.314 cSt(20 °C)
bp
58.8 °C/1013 hPa
mp
-7.3 °C
solubility
35 g/L
density
3.12 g/cm3 at 20 °C (liquid)
storage temp.
15-25°C
SMILES string
[Br-]
InChI
1S/BrH/h1H/p-1
InChI key
CPELXLSAUQHCOX-UHFFFAOYSA-M
General description
for synthesis
Application
Bromine can be used as an oxidizing agent for the oxidation of:
Bromine can also be used along with other co-reactants such as hexamethylphosphoric triamide (HMPA) and bis(tributyltin) oxide (HBD) to selectively oxidize secondary alcohols. However, bromine/nickel carboxylates convert 1,4-diols to γ-butyrolactones by selective oxidation of the primary alcohols.
- Primary alcohols to either aldehydes or esters and secondary alcohols to give ketones.
- Alcohols or diols to tetrahydrofurans in the presence of silver(I) salts.
- Enediol bis-trimethylsilyl ethers to α-diketones.
- Aldehydes to esters in the presence of alcohol solvents and sodium bicarbonate buffer.
- Aliphatic and aromatic thiols to disulfides.
Bromine can also be used along with other co-reactants such as hexamethylphosphoric triamide (HMPA) and bis(tributyltin) oxide (HBD) to selectively oxidize secondary alcohols. However, bromine/nickel carboxylates convert 1,4-diols to γ-butyrolactones by selective oxidation of the primary alcohols.
Analysis Note
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signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1A
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
hcodes
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials