24127
叔丁醇
≥99% (GC)
别名:
2-甲基-2-丙醇, 三甲基甲醇, 第三丁醇
蒸汽密度
2.5 (vs air)
质量水平
蒸汽压
31 mmHg ( 20 °C)
44 mmHg ( 26 °C)
方案
≥99% (GC)
表单
liquid
自燃温度
896 °F
expl. lim.
8 %
技术
GC/GC: suitable
杂质
≤0.001% free acid (as C3H7COOH)
≤0.001% non-volatile matter
≤0.1% water (Karl Fischer)
折射率
n20/D 1.387 (lit.)
pH值(酸碱度)
7 (20 °C)
沸点
83 °C (lit.)
mp
23-26 °C (lit.)
密度
0.775 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)(C)O
InChI
1S/C4H10O/c1-4(2,3)5/h5H,1-3H3
InChI key
DKGAVHZHDRPRBM-UHFFFAOYSA-N
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相关类别
一般描述
叔-丁醇是一种叔醇。过硫酸钾水溶液在叔丁醇存在下,可在20℃,254nm光照下进行光解,得到硫酸氢。
应用
叔-丁醇可用于制备碳水化合物脂肪酸酯。 它可以在通过脂肪酶催化反应从废烹饪棕榈油(WCPO)中生产脂肪酸甲酯(FAME)期间用作反应介质。
在氧化锆负载的12-钨磷酸存在下,它可用于对甲酚的正丁化反应。2-叔-丁基-对-甲酚(TBC)、2,6-二-叔-丁基 -对-甲酚(DTBC)和 叔-丁基-对-甲苯基醚(醚)分贝为丁基化反应形成的产物。
在氧化锆负载的12-钨磷酸存在下,它可用于对甲酚的正丁化反应。2-叔-丁基-对-甲酚(TBC)、2,6-二-叔-丁基 -对-甲酚(DTBC)和 叔-丁基-对-甲苯基醚(醚)分贝为丁基化反应形成的产物。
警示用语:
Danger
危险分类
Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Central nervous system, Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
59.0 °F - closed cup
闪点(°C)
15 °C - closed cup
法规信息
危险化学品
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