901169
trans-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride
Synonym(s):
trans-(PPh2Me)2Ni(o-tolyl)Cl
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SMILES string
Cl[Ni](PC([H])([H])[H])(P(C1=C([H])C([H])=C([H])C([H])=C1[H])(C2=C([H])C([H])=C([H])C([H])=C2[H])C([H])([H])[H])C3=C(C([H])([H])[H])C([H])=C([H])C([H])=C3[H].[H]C4=C(C5=C([H])C([H])=C([H])C([H])=C5[H])C([H])=C([H])C([H])=C4[H]
form
powder or solid
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
mp
152-157 °C
Application
Other Notes
Legal Information
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Articles
The Jamison group has developed a library of bench-stable phosphine-containing nickel(II) precatalysts that are converted into active catalysts in situ.
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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Jamison group focuses on new reaction development for organic synthesis, pioneering air-stable nickel precatalysts.
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