903698
1-Isopropyl-4-methyl-5-norbornene
Synonym(s):
1-Isopropyl-4-methylbicyclo[2.2.1]hept-2-en
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About This Item
Empirical Formula (Hill Notation):
C11H18
CAS Number:
Molecular Weight:
150.26
UNSPSC Code:
12352200
Form:
liquid
form
liquid
reaction suitability
reaction type: C-H Activation, reagent type: catalyst
storage temp.
2-8°C
Application
1-Isopropyl-4-methyl-5-norbornene is a norbornene ligand developed in the lab of Guanbing Dong for us in norbornene/palladium catalysis. The catalytic system of 1-Isopropyl-4-methyl-5-norbornene, [PdCl(allyl)]2 (683396), and RuPhos (663131) can be used for the site-selective ortho functionalization of aryl iodides.1
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Jianchun Wang et al.
Nature chemistry, 10(8), 866-872 (2018-06-27)
Achieving site-selectivity in arene functionalization that is complementary to the site-selectivity from electrophilic aromatic substitution reactions has been a long-standing quest in organic synthesis. Palladium/norbornene cooperative catalysis potentially offers a unique approach to this problem, but its use has been