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Merck
CN

237574

1,4-二溴-2,3-丁二醇

95%, mixture of R,R and S,S isomers

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线性分子式:
BrCH2CH(OH)CH(OH)CH2Br
化学文摘社编号:
分子量:
247.91
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Form:
solid
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InChI

1S/C4H8Br2O2/c5-1-3(7)4(8)2-6/h3-4,7-8H,1-2H2/t3-,4-/m1/s1

SMILES string

BrCC(O)C(O)CBr

InChI key

XOWDQAHYPSENAC-QWWZWVQMSA-N

assay

95%

form

solid

mp

82-84 °C (lit.)

General description

1,4-Dibromo-2,3-butanediol reacts with aqueous alkaline sodium arsenite to yield mixture of DL-2,3,4-trihydroxybutylarsonic acid and DL-2,3-dihydroxybutane-1,4-bis(arsonic acid).

Application

1,4-Dibromo-2,3-butanediol has been used in the preparation of diquaternary gemini surfactants.

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Surface activity and premicellar aggregation of some novel diquaternary gemini surfactants.
Rosen MJ and Liu L.
Journal of the American Oil Chemists' Society, 73(7), 885-890 (1996)
A M Kessling et al.
American journal of human genetics, 42(3), 458-467 (1988-03-01)
We have investigated the frequencies of RFLPs of the apolipoprotein (apo) AII gene and of the apo AI-CIII-AIV gene cluster in 109 men, selected from a random sample of 1,910 men aged 45-59 years, to cover a wide range of
Gerasimos M Tsivgoulis et al.
Chemistry and physics of lipids, 148(2), 97-104 (2007-06-09)
The reaction of DL-1,3-butadiene diepoxide and of DL-1,4-dibromo-2,3-butanediol with aqueous alkaline sodium arsenite, "Na(3)AsO(3)", gave mixtures of the title arsonic acids which can be separated by anion exchange resin. Characterization of by-products leads to a better understanding of these reactions.
Riikka Mäkelä et al.
The Journal of clinical endocrinology and metabolism, 88(8), 3823-3828 (2003-08-14)
Myeloperoxidase (MPO) is an oxidative enzyme present in phagocytes and atherosclerotic lesions. The MPO gene has a promoter polymorphism -463G/A, which leads to high (GG) and low expression (AG, AA) genotypes. We investigated the effect of long-term hormone replacement therapy

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