678503
(+)-Ipc2B(烯丙基)硼烷
1 M in pentane
别名:
(+)-B-二异松莰烯基烯丙基硼
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线性分子式:
(C10H17)2BCH2CH=CH2
化学文摘社编号:
分子量:
326.37
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22
产品名称
(+)-Ipc2B(烯丙基)硼烷, 1 M in pentane
SMILES string
C[C@@H]1[C@H](C[C@H]2C[C@@H]1C2(C)C)B(CC=C)[C@H]3C[C@H]4C[C@@H]([C@@H]3C)C4(C)C
InChI
1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m0/s1
InChI key
ZIXZBDJFGUIKJS-AXSQLCHVSA-N
optical activity
[α]20/D +14°, c = 1 in pentane
concentration
1 M in pentane
bp
35-36 °C
density
0.735 g/mL at 25 °C
storage temp.
−20°C
Quality Level
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Other Notes
本品冷却储藏时可能会变浑浊，不影响使用
Under refrigerator storage, these salt-free, Ipc2B(allyl) reagents do not show any appreciable decrease in selectivity is observed after several months. They exhibit excellent reactivity and reactions can be performed at 5°C, even in water.
Application
This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.
General description
http://www.sigmaaldrich.com/ifb/acta/v35/acta-vol35-2002.html#32
signalword
Danger
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-56.2 °F
flash_point_c
-49 °C
ppe
Eyeshields, Faceshields, Gloves
法规信息
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