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Merck
CN

62122

(R)-(+)-柠檬烯

greener alternative

technical, ~90% (sum of enantiomers, GC)

别名:

(+)-对薄荷-1,8-二烯, (+)-香芹烯, (R)-4-异丙烯基-1-甲基-1-环己烯

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关于此项目

经验公式（希尔记法）:
C10H16
化学文摘社编号:
5989-27-5
分子量:
136.23
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
329759709
EC Number:
227-813-5
Beilstein/REAXYS Number:
2204754
MDL number:
MFCD00062991
Assay:
~90% (sum of enantiomers, GC)
Form:
liquid

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InChI key

XMGQYMWWDOXHJM-JTQLQIEISA-N

InChI

1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1

SMILES string

CC(=C)[C@@H]1CCC(C)=CC1

vapor density

4.7 (vs air)

vapor pressure

<3 mmHg ( 14.4 °C)

grade

technical

assay

~90% (sum of enantiomers, GC)

form

liquid

optical activity

[α]20/D +112±5°, c = 10% in ethanol

expl. lim.

6.1 %

greener alternative product characteristics

Waste Prevention
Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
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sustainability

Greener Alternative Product

Quality Level

100

bp

176-177 °C (lit.)

solubility

water: insoluble

density

0.842 g/mL at 20 °C (lit.)

greener alternative category

Aligned,

storage temp.

2-8°C

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相关类别

General description

(R)-(+)-柠檬烯存在于柑橘类水果的果皮油中。它是技术产品和精细香料中最常用的香料。它是从莳萝属（印度莳萝）中提取的香精油的主要成分。外消旋柠檬烯通过指状青霉菌丝体，经过对映选择性和对映特异性转化为（R)-(+)-α-松油醇。研究了真菌对（R）-（+）-和（S）-（-）-柠檬烯的生物转化。
（R）-（+）-柠檬烯是柠檬烯的一种光学活性（R）形式。柠檬烯是一种10碳环己酮单萜。广泛应用于化妆品行业。

Application

（R）-（+）-柠檬烯已被用于研究柠檬烯对利什曼原虫的体外和体内作用。

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

123.8 °F - closed cup

flash_point_c

51 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB6294
SDBB5454
SDBB5229
BCCF2454
BCBZ1768

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Bioconversion of (R)-(+)-limonene by P. digitatum (NRRL 1202)
Tan Q, et al.
Process. Biochem., 33(1), 29-37 (1998)
J C Demyttenaere et al.
Phytochemistry, 57(2), 199-208 (2001-05-31)
The biotransformation of (R)-(-)- and (S)-(-)-limonene by fungi was investigated. More than 60 fungal cultures were screened for their ability to bioconvert the substrate, using solid phase microextraction as the monitoring technique. After screening, the best fungal strains were selected
Antimicrobial activity profiles of the two enantiomers of limonene and carvone isolated from the oils of Mentha spicata and Anethum sowa.
Aggarwal KK, et al.
Flavour and Fragrance Journal, 17(1), 59-63 (2002)
Denise C Arruda et al.
Biomedicine & pharmacotherapy = Biomedecine & pharmacotherapie, 63(9), 643-649 (2009-03-27)
Limonene is a monoterpene that has antitumoral, antibiotic and antiprotozoal activity. In this study we demonstrate the activity of limonene against Leishmania species in vitro and in vivo. Limonene killed Leishmania amazonensis promastigotes and amastigotes with 50% inhibitory concentrations of
Cedric S Graebin et al.
European journal of medicinal chemistry, 45(4), 1524-1528 (2010-02-02)
The synthesis and in vitro activity of R(+)-Limonene derivatives against Leishmania and Trypanosoma cruzi strains are reported. Seven compounds have shown better in vitro activity against Leishmania (V.)braziliensis than the standard drug pentamidine. Additionally, we have identified two promising new
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