118303
1,9-癸二烯
97%
别名:
Deca-1,9-diene
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关于此项目
线性分子式:
CH2=CH(CH2)6CH=CH2
化学文摘社编号:
分子量:
138.25
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39010313
UNSPSC Code:
12352100
EC Number:
216-711-6
MDL number:
Beilstein/REAXYS Number:
1697870
Assay:
97%
InChI key
NLDGJRWPPOSWLC-UHFFFAOYSA-N
InChI
1S/C10H18/c1-3-5-7-9-10-8-6-4-2/h3-4H,1-2,5-10H2
SMILES string
C=CCCCCCCC=C
assay
97%
Quality Level
bp
169 °C (lit.)
density
0.75 g/mL at 25 °C (lit.)
functional group
allyl
General description
1,9-Decadiene acts as comonomer and undergoes acyclic diene metathesis (ADMET) copolymerization with 1, 5-hexadiene to form random linear polybutadiene –polyoctenamer copolymers. It undergoes ADMET copolymerization with divinyltetraethoxydisiloxane to yield siloxylene–vinylene–alkenylene copolymer.
Application
1,9-Decadiene was used in synthesis and characterization of new telechelic polyoctenamers prepared by ADMET polymerization using Grubbs catalyst.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Acute 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
105.8 °F - closed cup
flash_point_c
41 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
ADMET copolymerization of divinyltetraethoxydisiloxane with 1, 9-decadiene catalyzed by Grubbs' catalyst.
Malecka E, et al.
J. Mol. Catal. A: Chem., 190(1), 27-31 (2002)
Synthesis of ABA triblock copolymers via acyclic diene metathesis polymerization and living polymerization of a-amino acid-N-carboxyanhydrides.
Brzezinska KR and Deming TJ.
Macromolecules, 34(13), 4348-4354 (2001)
Brent L Lee et al.
The Journal of chemical physics, 144(24), 245103-245103 (2016-07-03)
The time-resolved parallel artificial membrane permeability assay with fluorescence detection and comprehensive computer simulations are used to study the passive permeation of three aromatic dipeptides-N-acetyl-phenylalanineamide (NAFA), N-acetyltyrosineamide (NAYA), and N-acetyl-tryptophanamide (NATA) through a 1,2-dioleoyl-sn-glycero-3-phospocholine (DOPC) lipid bilayer. Measured permeation times
Acyclic diene metathesis copolymerization of 1, 5-hexadiene and 1, 9-decadiene.
Wagener KB, et al.
Macromolecules, 23(24), 5155-5157 (1990)
Alfredo E Cardenas et al.
The journal of physical chemistry. B, 116(9), 2739-2750 (2012-02-09)
Cellular transport machinery, such as channels and pumps, is working against the background of unassisted material transport through membranes. The permeation of a blocked tryptophan through a 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) membrane is investigated to probe unassisted or physical transport. The transport
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