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104493

氯乙酰氯

Name: 氯乙酰氯
Brand: ALDRICH

98%

别名:

Chloroacetic chloride

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关于此项目

线性分子式:

ClCH₂COCl

化学文摘社编号:

79-04-9

分子量:

112.94

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24846647

EC Number:

201-171-6

Beilstein/REAXYS Number:

605439

MDL number:

MFCD00000725

Assay:

98%

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属性

vapor density

3.9 (vs air)

Quality Level

200

vapor pressure

60 mmHg ( 41.5 °C)

assay

98%

refractive index

n20/D 1.453 (lit.)

bp

105-106 °C (lit.)

mp

−22 °C (lit.)

density

1.418 g/mL at 25 °C (lit.)

functional group

acyl chloride, chloro

SMILES string

ClCC(Cl)=O

InChI

1S/C2H2Cl2O/c3-1-2(4)5/h1H2

InChI key

VGCXGMAHQTYDJK-UHFFFAOYSA-N

说明

General description

氯乙酰氯被用作氯化试剂、酰化试剂、单氯酮烯的前体，以及环化的合成砌块。

氯乙酰氯在合成二级胺取代的氰基吡唑啉衍生物过程中引起氰基吡唑啉的酰化。

Application

氯乙酰氯可用于聚(甲基丙烯酸缩水甘油酯)的氯乙酰化和化学改性。氯乙酰氯用于研究大鼠和人肝微粒体对氯乙酰胺除草剂的体外代谢。氯乙酰氯用于合成一些具有抗利什曼原虫活性的新型喹啉衍生物。

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pictograms

GHS06,GHS08,GHS05,GHS09

signalword

Danger

hcodes

H301 + H311 + H331,H314,H372,H400

pcodes

P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P314

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1

target_organs

Lungs

supp_hazards

EUH014,EUH029

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

212.0 °F - closed cup

flash_point_c

100 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Comparative metabolism of chloroacetamide herbicides and selected metabolites in human and rat liver microsomes.

S Coleman et al.

Environmental health perspectives, 108(12), 1151-1157 (2001-01-03)

Acetochlor [2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamide], alachlor [N-(methoxymethyl)-2-chloro-N-(2, 6-diethyl-phenyl)acetamide], butachlor [N-(butoxymethyl)-2-chloro-N-(2,6-diethyl-phenyl)acetamide], and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamide] are pre-emergent herbicides used in the production of agricultural crops. These herbicides are carcinogenic in rats: acetochlor and alachlor cause tumors in the nasal turbinates, butachlor causes stomach tumors

Synthesis of a novel quinoline derivative, 2-(2-methylquinolin-4-ylamino)-N-phenylacetamide--a potential antileishmanial agent.

Niranjan P Sahu et al.

Bioorganic & medicinal chemistry, 10(6), 1687-1693 (2002-04-09)

Some novel quinoline derivatives were prepared and tested for antileishmanial activity. 2-(2-Methylquinolin-4-ylamino)-N-phenylacetamide (2) was found to be significantly more active than the standard antileishmanial drug sodium antimony gluconate (SAG) in reducing the parasite load both in the spleen and liver

Biologically active polymers: synthesis and antimicrobial activity of modified glycidyl methacrylate polymers having a quaternary ammonium and phosphonium groups.

Kenawy el-R et al.

Journal of controlled release : official journal of the Controlled Release Society, 50(1-3), 145-152 (1998-08-01)

Polymers with antibacterial activity have been synthesized by chemical modification of poly(glycidyl methacrylate). The glycidyl methacrylate was polymerized by the free radical polymerization technique. The poly(glycidyl methacrylate) was hydrolyzed and was chloroacetylated using chloroacetyl chloride. The chloroacetylated product was modified

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全球贸易项目编号

货号	GTIN
104493-5G	04061838671875
104493-500G	04061838671868
104493-100G	04061838671851