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10896

月桂酸乙烯酯

Name: 月桂酸乙烯酯
Brand: ALDRICH

Wacker Chemie AG, ≥98% (GC)

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关于此项目

线性分子式:

CH₃(CH₂)₁₀COOCH=CH₂

化学文摘社编号:

2146-71-6

分子量:

226.36

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

57646832

EC Number:

218-414-7

Beilstein/REAXYS Number:

1778369

MDL number:

MFCD00048421

Assay:

≥98% (GC)

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属性

Quality Level

100

assay

≥98% (GC)

manufacturer/tradename

Wacker Chemie AG

bp

254 °C/1013 hPa (lit.)

solubility

H₂O: slightly soluble 1 g/L at 20 °C

density

0.871 g/mL at 20 °C (lit.)

functional group

ester

SMILES string

CCCCCCCCCCCC(=O)OC=C

InChI

1S/C14H26O2/c1-3-5-6-7-8-9-10-11-12-13-14(15)16-4-2/h4H,2-3,5-13H2,1H3

InChI key

GLVVKKSPKXTQRB-UHFFFAOYSA-N

说明

General description

Vinyl laurate is a clear, colorless to light yellow colored liquid. The flash point is 125°C. It forms aqueous colloidal microgel by copolymerization with N-isopropylacrylamide. The enzymatic acylation of Avicel cellulose with vinyl laurate, a solvent free reaction system, was studied.

Application

Vinyl laurate was used in the synthesis of laurate and stearate esters of corn starch. It was used as the acyl donor during synthesis of sucrose laurate esters catalyzed by Bacillus pseudofirmus AL-89 . Vinyl laurate was also used in the preparation of chirally deuterated benzyl chlorides.

Other Notes

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存储类别

10 - Combustible liquids

wgk

WGK 1

flash_point_f

257.0 °F

flash_point_c

125 °C

ppe

Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

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Synthesis of sucrose laurate using a new alkaline protease.

Pedersen NR, et al.

Tetrahedron Asymmetry, 14(6), 667-673 (2003)

Synthesis of higher fatty acid starch esters using vinyl laurate and stearate as reactants.

Junistia L, et al.

Starch/Staerke, 60(12), 667-675 (2008)

Chirally deuterated benzyl chlorides from benzyl alcohols via hexachloroacetone/polymer-supported triphenylphosphine: synthesis of protected (2S, 3S)-[3-(2)H, (15)N]-tyrosine.

Derek W Barnett et al.

Journal of labelled compounds & radiopharmaceuticals, 56(1), 6-11 (2013-11-29)

Chirally deuterated benzyl chlorides were prepared using novel, general hexachloroacetone/polymer-supported triphenylphosphine treatment of chirally deuterated benzyl alcohols. Doubly labeled protected tyrosine was obtained in 62% yield with 86% de at the α-carbon and 82% de at the β-carbon. Key in

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