110485
反式-5-癸烯
98%
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关于此项目
线性分子式:
CH3(CH2)3CH=CH(CH2)3CH3
化学文摘社编号:
分子量:
140.27
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
231-080-7
MDL number:
产品名称
反式-5-癸烯, 98%
InChI key
UURSXESKOOOTOV-MDZDMXLPSA-N
InChI
1S/C10H20/c1-3-5-7-9-10-8-6-4-2/h9-10H,3-8H2,1-2H3/b10-9+
SMILES string
[H]\C(CCCC)=C(\[H])CCCC
assay
98%
refractive index
n20/D 1.424 (lit.)
bp
170 °C/750 mmHg (lit.)
density
0.74 g/mL at 25 °C (lit.)
Quality Level
Application
trans-5-Decene has been used to characterize the effect of cyclization and size on the stability of Criegee intermediates formed in ozonolysis. It has been added to phenoxathiin cation radical in acetonitrile solution to form bis(10-phenoxathiiniumyl) alkane adducts.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
114.8 °F - closed cup
flash_point_c
46 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Greg T Drozd et al.
The journal of physical chemistry. A, 115(17), 4381-4387 (2011-04-12)
Ozonolysis is a key reaction in atmospheric chemistry, although important details of the behavior of the ozonolysis intermediates are not known. The key intermediate in ozonolysis, the Criegee intermeiate (CI), is known to quickly isomerize, with the favored unimolecular pathway
Keisean A J M Stevenson et al.
Journal of separation science, 42(11), 2013-2022 (2019-04-10)
Thermodynamics-based models have been demonstrated to be useful for predicting retention time and peak widths in gas chromatography and two-dimensional gas chromatography separations. However, the collection of data to train the models can be time consuming, which lessens the practical
Bing-Jun Zhao et al.
The Journal of organic chemistry, 72(16), 6154-6161 (2007-07-03)
Addition of phenoxathiin cation radical (PO*+) to acyclic alkenes in acetonitrile (MeCN) solution occurred stereospecifically to form bis(10-phenoxathiiniumyl)alkane adducts. Stereospecific trans addition is ascribed to the intermediacy of an episulfonium cation radical. The alkenes used were cis- and trans-2-butene, cis-
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