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Merck
CN

112798

Sigma-Aldrich

二聚环戊二烯

95% dicyclopentadiene basis

别名:

4,7-亚甲基-3a,4,7,7a-四氢茚, DCPD, 环戊二烯二聚体

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经验公式(希尔记法):
C10H12
化学文摘社编号:
分子量:
132.20
Beilstein:
1904092
EC 号:
MDL编号:
UNSPSC代码:
12352200
PubChem化学物质编号:
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方案

95% dicyclopentadiene basis

包含

200 ppm p-tert-butylcatechol as inhibitor

沸点

170 °C (lit.)

mp

33 °C (lit.)

密度

0.986 g/mL at 25 °C (lit.)

SMILES字符串

C1C=CC2C3CC(C=C3)C12

InChI

1S/C10H12/c1-2-9-7-4-5-8(6-7)10(9)3-1/h1-2,4-5,7-10H,3,6H2/t7-,8+,9?,10?/m0/s1

InChI key

HECLRDQVFMWTQS-AFWXGSBKSA-N

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警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

89.6 °F - closed cup

闪点(°C)

32 °C - closed cup

法规信息

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L G Stehmeier et al.
Biodegradation, 10(2), 135-148 (1999-08-31)
Dicyclopentadiene (DCPD) is formed during the pyrolysis of alkanes to produce olefins suitable for manufacturing synthetic polymers. DCPD has an irritating odor with a 5 ppb detection level that provides the impetus for remediation efforts. One method of destroying odors
Abhinaba Gupta et al.
Chemical communications (Cambridge, England), 47(37), 10236-10238 (2011-08-23)
Thimbles composed of polydicyclopentadiene retained Pd and phosphines used in Buchwald-Hartwig and Sonogashira coupling reactions but allowed the products to permeate. The products were isolated in high yields on the exteriors of the thimbles with no detectable contamination from phosphine
Aaron C Jackson et al.
Macromolecular rapid communications, 32(1), 82-87 (2011-03-25)
A generalized silica coating scheme is used to functionalize and protect sub-micron and micron size dicyclopentadiene monomer-filled capsules and polymer-protected Grubbs' catalyst particles. These capsules and particles are used for self-healing of microscale damage in an epoxy-based polymer. The silica
Metal-mediated retro Diels-Alder of dicyclopentadiene derivatives: a convenient synthesis of [(Cp-R)M(CO)3] (M = 99mTc, Re) complexes.
Yu Liu et al.
Journal of the American Chemical Society, 130(5), 1554-1555 (2008-01-12)
Timothy C Mauldin et al.
Journal of the Royal Society, Interface, 4(13), 389-393 (2007-01-26)
While original epoxy resin-based self-healing systems used the commercially available endo-isomer of dicyclopentadiene (DCPD), the exo-stereoisomer is known to have much faster olefin metathesis reaction rates with first-generation Grubbs' catalyst. Here, we measure the energy to failure of healed specimens

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