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115819

2,2'-联苯酚

Name: 2,2'-联苯酚
Brand: ALDRICH

99%

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别名:

2,2′-二羟基联苯, 2,2′-联苯二酚, 2,2′-联苯酚

线性分子式:

HOC₆H₄C₆H₄OH

CAS号:

1806-29-7

分子量:

186.21

Beilstein:

1638363

EC 号:

217-303-0

MDL编号:

MFCD00002210

PubChem化学物质编号:

24847240

NACRES:

NA.23

质量水平

100

检测方案

99%

形式

solid

bp

315 °C (lit.)

mp

108-110 °C (lit.)

SMILES string

Oc1ccccc1-c2ccccc2O

InChI

1S/C12H10O2/c13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8,13-14H

InChI key

IMHDGJOMLMDPJN-UHFFFAOYSA-N

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

309.2 °F - (External MSDS)

闪点(°C)

154 °C - (External MSDS)

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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Metabolism of 2,2'-dihydroxybiphenyl by Pseudomonas sp. strain HBP1: production and consumption of 2,2',3-trihydroxybiphenyl.

H P Kohler et al.

Journal of bacteriology, 175(6), 1621-1628 (1993-03-01)

Cells of Pseudomonas sp. strain HBP1 grown on 2-hydroxy- or 2,2'-dihydroxybiphenyl contain NADH-dependent monooxygenase activity that hydroxylates 2,2'-dihydroxybiphenyl. The product of this reaction was identified as 2,2',3-trihydroxybiphenyl by 1H nuclear magnetic resonance and mass spectrometry. Furthermore, the monooxygenase activity also

Perylene bisimides with rigid 2,2'-biphenol bridges at bay area as conjugated chiral platforms.

Zengqi Xie et al.

Organic letters, 12(14), 3204-3207 (2010-06-22)

Facile nucleophilic substitution of two chlorine atoms by 2,2'-biphenol at one of the two bay areas (1,12- and 6,7-positions) of core-tetrachlorinated perylene bisimide afforded a novel, completely desymmetrized perylene bisimide building block, which could be further functionalized by substitution of

Peroxidase/hydrogen peroxide--or bone marrow homogenate/hydrogen peroxide--mediated activation of phenol and binding to protein.

V V Subrahmanyam et al.

Xenobiotica; the fate of foreign compounds in biological systems, 20(12), 1369-1378 (1990-12-01)

1. 14C-Phenol was metabolized by rat bone marrow homogenate and H2O2. The homogenate catalyst, however, was inactivated by preincubation with H2O2, presumably due to inactivation of the enzyme(s) involved in phenol metabolism. 2. The majority of the metabolized 14C-phenol was

Cytotoxic neolignans: an SAR study.

Zwe-Ling Kong et al.

Bioorganic & medicinal chemistry letters, 15(1), 163-166 (2004-12-08)

The neolignans, magnolol 1 and honokiol 2 have been reported to inhibit the growth of several tumor cell lines in vitro and in vivo. The chemical structure of magnolol and honokiol consists of biphenyl skeleton with phenolic and allylic functionalities.

Double N-arylation of primary amines: carbazole synthesis from 2,2'-biphenyldiols.

Atsushi Kuwahara et al.

The Journal of organic chemistry, 70(2), 413-419 (2005-01-18)

The double N-arylation of primary amines with 2,2'-biphenylylene ditriflates was investigated for the synthesis of multisubstituted carbazoles. Palladium complexes supported by 2-dicyclohexylphosphino-2'-methylbiphenyl or Xantphos [4,5-bis(diphenylphosphino)-9,9-dimethylxanthene] were found to be efficient catalysts for the reaction. The catalysts allow the use of

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