124664
对溴苯乙腈
98%
别名:
4-溴苄腈
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关于此项目
线性分子式:
BrC6H4CH2CN
化学文摘社编号:
分子量:
196.04
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
98%
表单
solid
mp
47-49 °C (lit.)
官能团
bromo
nitrile
SMILES字符串
Brc1ccc(CC#N)cc1
InChI
1S/C8H6BrN/c9-8-3-1-7(2-4-8)5-6-10/h1-4H,5H2
InChI key
MFHFWRBXPQDZSA-UHFFFAOYSA-N
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一般描述
4-Bromophenylacetonitrile undergoes reduction using 1,1,3,3-tetramethyldisiloxane activated by a non-toxic titanium(IV) isopropoxide to yield 4-bromophenylethylamine.
应用
4-Bromophenylacetonitrile has been used in the synthesis of :
- new fluorene-based alternating polymers
- light-emitting copolymer, poly(N 4,N 4-bis-(4-phenyl)-N 4,N 4′-bis-[4-(2-ethylhexyloxy)phenyl]-biphenyl-4,4′-diamine-co-1,2-bis(4′-phenyl)-1-(9′′,9′′-dihexyl-3-fluorenyl)ethane) using a Yamamoto coupling reaction
- N-methyl-3,4-bis(4-(N-(1-naphthyl)phenylamino)phenyl)maleimide, a novel non-doped red organic light-emitting diode (OLED) material
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
A mild and efficient method for the reduction of nitriles.
Laval S, et al.
Tetrahedron Letters, 50(50), 7005-7007 (2009)
Polymeric light emitting properties and structural relationships of fluorene-based conjugated copolymers containing various hole transporting derivatives.
Park JH, et al.
Organic Electronics, 8(2), 272-285 (2007)
Synthesis and device performance of new efficient blue copolymers containing biphenylenevinylene and triphenyldiamine.
Oh DH, et al.
Macromolecular Research, 19(6), 629-634 (2011)
Hsiu-Chih Yeh et al.
Chemical communications (Cambridge, England), (20)(20), 2632-2633 (2003-11-05)
Bright (maximum 10034 cd m(-2), 455 cd m(-2) at 20 mA cm(-2)) and efficient (maximum 2.4% at 4 mA cm(-2)) red (lambda(max)el 634-636 nm) organic light-emitting diodes employ arylamino-substituted fumaronitrile as the novel host emitter, which is readily prepared and
Yanqiu Liu et al.
Colloids and surfaces. B, Biointerfaces, 159, 596-604 (2017-09-01)
Surface properties of nanoparticles (NPs) have a huge influence on their biological activities. In this work, we report to use mesoporous silica nanoshell surface to regulate the cellular internalization rate and intracellular fate of fluorescent organic NPs for highly improved
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