126632
1,2-二硝基苯
97%
别名:
o-Dinitrobenzene
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关于此项目
线性分子式:
C6H4(NO2)2
化学文摘社编号:
分子量:
168.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-431-8
Beilstein/REAXYS Number:
642224
MDL number:
Assay:
97%
Form:
solid
InChI key
IZUKQUVSCNEFMJ-UHFFFAOYSA-N
InChI
1S/C6H4N2O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H
SMILES string
[O-][N+](=O)c1ccccc1[N+]([O-])=O
assay
97%
form
solid
bp
319 °C/773 mmHg (lit.)
Quality Level
functional group
nitro
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General description
1,2-Dinitrobenzene (o-Dinitrobenzene) is one of the nitroaromatic compounds present in urine which has been studied using gas chromatography-mass spectrometry-selected ion monitoring methods†. The electrochemistry of 1,2-dinitrobenzene (o-Dinitrobenzene) is strongly affected by 1,3-diphenylurea.
Application
- A highly divergent Pictet-Spengler approach for pyrrolo quinoxalines from aryl amine using 1,2-dinitrobenzene as an oxidant: Discusses the utility of 1,2-dinitrobenzene as an oxidant in organic synthesis, relevant for developing novel pharmaceuticals (Pardeshi et al., 2019).
signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
302.0 °F - closed cup
flash_point_c
150 °C - closed cup
法规信息
非剧毒-急性毒性1
危险化学品
此项目有
Young-Wook Cho et al.
Biochimica et biophysica acta, 1574(3), 399-402 (2002-05-09)
A second glutathione S-transferase gene (GST II) was isolated from the chromosomal DNA of the fission yeast Schizosaccharomyces pombe. The nucleotide sequence determined contains 1908 bp including an open reading frame of 230 amino acids that would encode a protein
G V Gonzalez-Stawinski et al.
Clinical immunology (Orlando, Fla.), 98(2), 175-179 (2001-02-13)
Blocking the elicited humoral immune response has proven useful in treating individuals with autoimmune disorders or those who are at risk of developing antibodies which might be pathologic, e.g., transplant patients. Unfortunately, humoral immunity has evaded efforts at ablation and
Junro Shinoda et al.
Biochemical and biophysical research communications, 364(2), 258-263 (2007-10-24)
Metazoan arrestin proteins bind to seven-transmembrane proteins, mediate their internalization and play central roles in the subsequent signal transduction pathway. In Saccharomyces cerevisiae, there are several arrestin-related proteins. One of those proteins, Rod1, has been identified to have the ability
Amelie Lupp et al.
Experimental and toxicologic pathology : official journal of the Gesellschaft fur Toxikologische Pathologie, 55(2-3), 107-119 (2003-11-19)
The aim of the present study was to characterise developmental changes in glutathione S-transferase (GST) isoforms expression and in glutathione conjugation capacity in intrasplenic liver tissue transplants. For this purpose, syngenic fetal liver tissue suspensions were transplanted into the spleens
A Maroziene et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 56(11-12), 1157-1163 (2002-02-12)
We have examined the structure-activity relationships in methemoglobin (MetHb) formation by high explosives 2,4,6-trinitrotoluene (TNT), 2,4,6-trinitrophenyl-N-nitramine (tetryl) and 2,4,6-trinitrophenyl-N-nitraminoethylnitrate (pentryl), and a number of model nitrobenzenes. In lysed human erythrocytes the rate constants of oxyhemoglobin (OxyHb) oxidation increased with an
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