127574
3,4-环氧-1-丁烯
98%
别名:
2-乙烯基环氧乙烷, 3,4-环氧-1-丁烯, 环氧丁烯
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关于此项目
经验公式（希尔记法）:
C4H6O
化学文摘社编号:
分子量:
70.09
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
213-210-4
Beilstein/REAXYS Number:
103170
MDL number:
InChI key
GXBYFVGCMPJVJX-UHFFFAOYSA-N
InChI
1S/C4H6O/c1-2-4-3-5-4/h2,4H,1,3H2
SMILES string
C=CC1CO1
assay
98%
form
liquid
refractive index
n20/D 1.417 (lit.)
bp
65-66 °C (lit.)
density
0.87 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-58.0 °F - closed cup
flash_point_c
-50 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Stereoselective ring expansion of vinyl oxiranes: mechanistic insights and natural product total synthesis.
Matthew Brichacek et al.
Angewandte Chemie (International ed. in English), 49(9), 1648-1651 (2010-02-06)
Eduardo Cemeli et al.
Mutation research, 664(1-2), 69-76 (2009-05-12)
The toxicity of butadiene and styrene is exerted by their metabolites. Such metabolites have been extensively scrutinized at the in vitro level demonstrating evident genotoxic properties. In monitoring, a diverse range of outcomes has been produced. Additionally, epidemiological studies in
Thomas J L Mustard et al.
Journal of the American Chemical Society, 135(4), 1471-1475 (2013-01-01)
Density functional theory computations of the Cu-catalyzed ring expansion of vinyloxiranes is mediated by a traceless dual Cu(I)-catalyst mechanism. Overall, the reaction involves a monomeric Cu(I)-catalyst, but a single key step, the Cu migration, requires two Cu(I)-catalysts for the transformation.
Some insights into the mode of action of butadiene by examining the genotoxicity of its metabolites.
A D Kligerman et al.
Chemico-biological interactions, 166(1-3), 132-139 (2006-05-16)
1,3-Butadiene (BTD) is an important commodity chemical and air pollutant that has been shown to be a potent carcinogen in mice, and to a lesser extent, a carcinogen in rats. To better assess butadiene's carcinogenic risk to humans, it is
L Recio et al.
Chemico-biological interactions, 135-136, 325-341 (2001-06-09)
1,3-Butadiene (BD) is a multisite carcinogen and is mutagenic in multiple tissues of B6C3F1 mice. BD is bioactivated to at least three directly mutagenic metabolites: 1,2-epoxybutene (EB), 1,2-epoxy-3,4-butanediol (EBD), and 1,2,3,4-diepoxybutane (DEB). However, the contribution of these individual metabolites to
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