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线性分子式:
CH3C[=NSi(CH3)3]OSi(CH3)3
化学文摘社编号:
分子量:
203.43
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
233-892-7
Beilstein/REAXYS Number:
1306669
MDL number:
产品名称
N,O-双(三甲基甲硅烷基)乙酰胺, synthesis grade, ≥95%
InChI key
SIOVKLKJSOKLIF-CMDGGOBGSA-N
InChI
1S/C8H21NOSi2/c1-8(9-11(2,3)4)10-12(5,6)7/h1-7H3/b9-8+
SMILES string
C\C(O[Si](C)(C)C)=N/[Si](C)(C)C
grade
synthesis grade
assay
≥95%
form
liquid
refractive index
n20/D 1.417 (lit.)
bp
71-73 °C/35 mmHg (lit.)
density
0.832 g/mL at 20 °C (lit.)
functional group
amine
Quality Level
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Application
可用于对多糖硫酸酯进行区域选择性脱硫的试剂。也可用于制备碳水化合物和醇的三甲基硅醚。
对水果中酚酸进行 GC-MS 分析的衍生化试剂。
Features and Benefits
牛血清白蛋白具有良好的吸湿性。
General description
N,O-二(三甲基硅基)乙酰胺(BSA)是一种有效的硅基化剂,用于保护酰胺、胺、醇、羧酸、烯醇和酚类。它也可用作 Tsuji–Trost 反应中的布朗斯台德碱前体。此外,它还可以在核苷、肽和杂环的生产过程中激活不同的官能团。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
111.2 °F - closed cup
flash_point_c
44 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Carbohydrate Research, 237, 313-313 (1992)
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Murthy YLN, et al.
Arabian Journal of Chemistry, 9, S1740-S1746 (2016)
Mohammad Saraji et al.
Journal of separation science, 29(9), 1223-1229 (2006-07-13)
A simple analytical procedure based on single-drop microextraction combined with in-syringe derivatization and GC-MS was developed for determination of some phenolic acids in fruits and fruit juices. Cinnamic acid, o-coumaric acid, caffeic acid, and p-hydroxybenzoic acid were used as model
N, O-Bis (trimethylsilyl) acetamide
Claraz A
Synlett, 24(5), 657-658 (2013)
Olga Moiseeva et al.
Cell cycle (Georgetown, Tex.), 14(15), 2408-2421 (2015-06-02)
Expression of oncogenes or short telomeres can trigger an anticancer response known as cellular senescence activating the p53 and RB tumor suppressor pathways. This mechanism is switched off in most tumor cells by mutations in p53 and RB signaling pathways.
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