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133973

溴乙酸乙酯

reagent grade, 98%

别名:

Bromoacetic acid ethyl ester, Ethyl 2-bromoacetate

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关于此项目

线性分子式:
BrCH2COOC2H5
化学文摘社编号:
105-36-2
分子量:
167.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24848125
EC Number:
203-290-9
Beilstein/REAXYS Number:
506456
MDL number:
MFCD00000191
Assay:
98%
Form:
liquid
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grade

reagent grade

Quality Level

200

vapor pressure

2.6 mmHg ( 25 °C)

assay

98%

form

liquid

refractive index

n20/D 1.451 (lit.)

bp

159 °C (lit.)

solubility

water: insoluble

density

1.506 g/mL at 25 °C (lit.)

functional group

bromo, ester

SMILES string

CCOC(=O)CBr

InChI

1S/C4H7BrO2/c1-2-7-4(6)3-5/h2-3H2,1H3

InChI key

PQJJJMRNHATNKG-UHFFFAOYSA-N

General description

溴代乙酸乙酯常在有机合成中用作为烷化剂和酰化试剂。溴代乙酸乙酯与对叔丁基杯[4]芳烃进行衍生化反应，生成1,3-二酯取代的杯[4]芳烃。它还与芳基硼酸在氧化铜(I)共催化下发生Suzuki型交叉偶联反应。

Application

溴乙酸乙酯用于在水性介质中制备可逆光敏香豆素稳定的聚合物纳米颗粒，其可用作可检测的药物载体。

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pictograms

FlameSkull and crossbones
GHS02,GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

116.6 °F - closed cup

flash_point_c

47 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB3487
STBK8715
MKCS7144
STBK2621
MKCN2346

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Jae Woo Chung et al.
Small (Weinheim an der Bergstrasse, Germany), 8(11), 1693-1700 (2012-03-29)
The ability to create aqueous suspended stable nanoparticles of the hydrophobic homopolymer poly(ϵ-caprolactone) end-functionalized with coumarin moieties (CPCL) is demonstrated. Nanoparticles of CPCL are prepared in a continuous manner using nanoprecipitation. The resulting nanoparticles are spherical in morphology, about 40
Unusual pathway of alkylation of 2-(4-bromobenzylidene)-p-menthan-3-one with ethyl bromoacetate
AI Krivoshei, et al.
Russian Chemical Bulletin, 56, 2506-2509 (2007)
Monika Wujec et al.
The journal of physical chemistry. B, 112(39), 12414-12419 (2008-09-11)
The influence of the implicit solvent model on transition state structures of two S N2 reactions of biochemical importance is presented. In the considered methyl transfer reaction, we show experimentally that the rate constant in blood serum is about 60%
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全球贸易项目编号

货号GTIN
133973-5G04061837374678
133973-500G04061838729712
133973-100G04061838729705