139130
2-氯丙酸甲酯
97%
别名:
(±)-2-氯丙酸甲酯
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关于此项目
线性分子式:
CH3CHClCOOCH3
化学文摘社编号:
分子量:
122.55
Beilstein:
1421535
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
蒸汽密度
4.22 (vs air)
蒸汽压
5.25 mmHg ( 20 °C)
方案
97%
expl. lim.
19 %
折射率
n20/D 1.417 (lit.)
沸点
132-133 °C (lit.)
密度
1.075 g/mL at 25 °C (lit.)
SMILES字符串
COC(=O)C(C)Cl
InChI
1S/C4H7ClO2/c1-3(5)4(6)7-2/h3H,1-2H3
InChI key
JLEJCNOTNLZCHQ-UHFFFAOYSA-N
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一般描述
Methyl 2-chloropropionate is the initiating/catalyst system during the atom transfer radical polymerization of N,N-dimethylacrylamide, N-isopropylacrylamide and N-vinylpyrrolidone.
应用
Methyl 2-chloropropionate was used as initiator during the synthesis of acrylamide homopolymers and acrylamide-N-isopropylacrylamide block copolymers.
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
100.4 °F - closed cup
闪点(°C)
38 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
A I Gurova et al.
Gigiena truda i professional'nye zabolevaniia, (5)(5), 36-38 (1992-01-01)
Reports of MACs for carboxylic acid derivatives as sodium methoxyacetate (SMOA), methyl chlorpropionate (MCP) and acetoacetic ether (AAE). SMOA shows low toxicity, no cumulation and specific action MCP demonstrates moderate toxicity, low cumulation no specific action in concentrations close to
Controllable synthesis of poly (N-vinylpyrrolidone) and its block copolymers by atom transfer radical polymerization.
Lu X, et al.
Polymer, 48(10), 2835-2842 (2007)
J L Rakels et al.
Enzyme and microbial technology, 15(12), 1051-1056 (1993-12-01)
The enantiomeric ratio (E) is commonly used to characterize the enantioselectivity in enzyme-catalyzed kinetic resolution. In this paper this parameter is directly derived from the enantiomeric excess of substrate and product. This is formally more correct than using Chen's equation
Copolymerization of N, N-dimethylacrylamide with n-butyl acrylate via atom transfer radical polymerization.
Neugebauer D and Matyjaszewski K.
Macromolecules, 36(8), 2598-2603 (2003)
Thermal response of narrow-disperse poly (N-isopropylacrylamide) prepared by atom transfer radical polymerization.
Xia Y, et al.
Macromolecules, 38(14), 5937-5943 (2005)
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