质量水平
方案
95%
沸点
248 °C/740 mmHg (lit.)
mp
67-69 °C (lit.)
官能团
chloro
SMILES字符串
Oc1cc(Cl)c(Cl)cc1Cl
InChI
1S/C6H3Cl3O/c7-3-1-5(9)6(10)2-4(3)8/h1-2,10H
InChI key
LHJGJYXLEPZJPM-UHFFFAOYSA-N
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一般描述
2,4,5-Trichlorophenol (2,4,5-TCP) is employed as a raw material in the preparation of various biocides.
应用
2,4,5-trichlorophenol can be used as a starting material to synthesize:
- Hexachlorophene, a fungicide, by the reaction with formaldehyde in the presence of concentrated H2SO4.
- 2,4,5-trichlorophenoxyacetic acid (2,4,5-T), a herbicide.
- N-Benzyl-2-(2,4,5-trichlorophenoxy)acetamide, which is used as an intermediate to prepare 4-benzyl-6,7-dichloro-2H-benzo[b][1,4]oxazin-3(4H)-one via Smiles rearrangement.
The product has been used to study its sorption onto montmorillonite based sorbents.
免责声明
“The product is not intended for use as a biocide under global biocide regulations, including but not limited to US EPA′s Federal Insecticide Fungicide and Rodenticide Act, European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR) and others."
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
271.4 °F - closed cup
闪点(°C)
133.0 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
此项目有
The Lethal Interaction and Formation of a Lipophilic Ternary Complex between 2, 4, 5-Trichlorophenol and the Cu (II)- Bis (1, 10-phenanthroline) Complex
Zhu Ben-Zhan
Chemical Research in Toxicology, 14(2), 222-227 (2001)
Microwave-assisted Synthesis of 2H-Benzo [b][1, 4] oxazin-3 (4H)-ones and 1H-Pyrido [2, 3-b][1, 4] oxazin-2 (3H)-ones via Smiles Rearrangement
Hua Zuo, et al.
Bulletin of the Korean Chemical Society,, 29(7), 1379-1385 (2008)
Photo-assisted degradation of 2, 4, 5-trichlorophenol by Electro-Fe (II)/Oxone{\textregistered} process using a sacrificial iron anode: Performance optimization and reaction mechanism
Wang YR and Chu Wei
Chemical Engineering Journal, 215, 643-650 (2013)
Organic Chemistry: With Biological Applications
Organic Chemistry (2011)
Brian N Webb et al.
The Journal of biological chemistry, 285(3), 2014-2027 (2009-11-17)
Burkholderia cepacia AC1100 completely degrades 2,4,5-trichlorophenol, in which an FADH(2)-dependent monooxygenase (TftD) and an NADH:FAD oxidoreductase (TftC) catalyze the initial steps. TftD oxidizes 2,4,5-trichlorophenol (2,4,5-TCP) to 2,5-dichloro-p-benzoquinone, which is chemically reduced to 2,5-dichloro-p-hydroquinone (2,5-DiCHQ). Then, TftD oxidizes the latter to
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