156515
2,4,5-三氯苯酚
95%
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关于此项目
线性分子式:
Cl3C6H2OH
化学文摘社编号:
分子量:
197.45
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-467-8
Beilstein/REAXYS Number:
607569
MDL number:
Assay:
95%
产品名称
2,4,5-三氯苯酚, 95%
InChI key
LHJGJYXLEPZJPM-UHFFFAOYSA-N
InChI
1S/C6H3Cl3O/c7-3-1-5(9)6(10)2-4(3)8/h1-2,10H
SMILES string
Oc1cc(Cl)c(Cl)cc1Cl
assay
95%
bp
248 °C/740 mmHg (lit.)
mp
67-69 °C (lit.)
functional group
chloro
Quality Level
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Application
2,4,5-trichlorophenol can be used as a starting material to synthesize:
- Hexachlorophene, a fungicide, by the reaction with formaldehyde in the presence of concentrated H2SO4.
- 2,4,5-trichlorophenoxyacetic acid (2,4,5-T), a herbicide.
- N-Benzyl-2-(2,4,5-trichlorophenoxy)acetamide, which is used as an intermediate to prepare 4-benzyl-6,7-dichloro-2H-benzo[b][1,4]oxazin-3(4H)-one via Smiles rearrangement.
The product has been used to study its sorption onto montmorillonite based sorbents.
Disclaimer
“The product is not intended for use as a biocide under global biocide regulations, including but not limited to US EPA′s Federal Insecticide Fungicide and Rodenticide Act, European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR) and others."
General description
2,4,5-Trichlorophenol (2,4,5-TCP) is employed as a raw material in the preparation of various biocides.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
271.4 °F - closed cup
flash_point_c
133.0 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
此项目有
Organic Chemistry: With Biological Applications
Organic Chemistry (2011)
The Lethal Interaction and Formation of a Lipophilic Ternary Complex between 2, 4, 5-Trichlorophenol and the Cu (II)- Bis (1, 10-phenanthroline) Complex
Zhu Ben-Zhan
Chemical Research in Toxicology, 14(2), 222-227 (2001)
Microwave-assisted Synthesis of 2H-Benzo [b][1, 4] oxazin-3 (4H)-ones and 1H-Pyrido [2, 3-b][1, 4] oxazin-2 (3H)-ones via Smiles Rearrangement
Hua Zuo, et al.
Bulletin of the Korean Chemical Society,, 29(7), 1379-1385 (2008)
Photo-assisted degradation of 2, 4, 5-trichlorophenol by Electro-Fe (II)/Oxone{\textregistered} process using a sacrificial iron anode: Performance optimization and reaction mechanism
Wang YR and Chu Wei
Chemical Engineering Journal, 215, 643-650 (2013)
Qiao Sun et al.
Environmental science & technology, 41(16), 5708-5715 (2007-09-19)
Density functional theory (DFT) calculations have been carried out to explore the potential energy surface (PES) associated with the gas-phase reaction between 2,4,5-trichlorophenol and CuO. A gas-phase model was constructed to account, from a theoretical perspective, for the most important
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