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Merck
CN

157333

3-氯苯甲醚

98%

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线性分子式:
ClC6H4OCH3
化学文摘社编号:
分子量:
142.58
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-642-7
Beilstein/REAXYS Number:
2041497
MDL number:
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产品名称

3-氯苯甲醚, 98%

InChI key

YUKILTJWFRTXGB-UHFFFAOYSA-N

InChI

1S/C7H7ClO/c1-9-7-4-2-3-6(8)5-7/h2-5H,1H3

SMILES string

COc1cccc(Cl)c1

assay

98%

form

liquid

refractive index

n20/D 1.536 (lit.)

bp

193 °C (lit.)

density

1.164 g/mL at 25 °C (lit.)

functional group

chloro

Quality Level

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Application

3-Chloroanisole was employed as starting reagent in the regioselective synthesis of 4- and 7-alkoxyindoles. It was also employed as electrolyte additive for the overcharging protection of Li-ion cell.

General description

One-step preparation of 3-chloroanisole from the corresponding 3-substituted nitrobenzene has been reported.

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

163.4 °F - closed cup

flash_point_c

73 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number

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Roberto Sanz et al.
The Journal of organic chemistry, 72(14), 5113-5118 (2007-06-15)
An efficient and regioselective synthesis of 4- and 7-alkoxyindoles has been developed from commercially available starting materials such as 3-halophenols and 3-chloroanisole. Directed ortho-metalation followed by two palladium-catalyzed processes, a Sonogashira coupling and a tandem amination/cyclization reaction, allows the synthesis
3-Chloroanisole for overcharge protection of a Li-ion cell.
Lee Y-G and Cho J.
Electrochimica Acta, 52(25), 7404-7408 (2007)
One-step preparation of some 3-substituted anisoles.
Zilberman J.
Organic Process Research & Development, 7(3), 303-305 (2003)

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