157872
1,3-二噻烷
97%
别名:
间二噻烷（7CI）, 间二噻烷（8CI）
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关于此项目
经验公式（希尔记法）:
C4H8S2
化学文摘社编号:
分子量:
120.24
Beilstein:
102534
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
表单
solid
mp
52-54 °C (lit.)
官能团
thioether
SMILES字符串
C1CSCSC1
InChI
1S/C4H8S2/c1-2-5-4-6-3-1/h1-4H2
InChI key
WQADWIOXOXRPLN-UHFFFAOYSA-N
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一般描述
1,3-二噻烷，一种受保护的甲醛阴离子当量，用作有用的标记合成子。
应用
以 1，3-二噻烷为脱氧剂，将亚砜脱氧成相应的硫化物。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
194.0 °F - closed cup
闪点(°C)
90 °C - closed cup
个人防护装备
Eyeshields, Gloves, type N95 (US)
Rodolfo A Martinez et al.
Journal of labelled compounds & radiopharmaceuticals, 57(5), 338-341 (2014-05-28)
The 1,3-dithiane is a protected formaldehyde anion equivalent that could serve as a useful labeled synthon. We report a facile synthesis of 1,3-[2-(13)C]- and 1,3-[2-(13)C, 2-(2)H2]dithiane in two steps from [(13)C]- or [(13) C, (2)H3 ]methyl phenyl sulfoxide. We have
Valerie J Peterson et al.
The Biochemical journal, 362(Pt 1), 173-181 (2002-02-07)
Apo and holo forms of retinoic acid receptors, and other nuclear receptors, display differential sensitivity to proteolytic digestion that likely reflects the distinct conformational states of the free and liganded forms of the receptor. We have developed a method for
Al-Monsur Jiaul Haque et al.
Chemical communications (Cambridge, England), (32)(32), 4865-4867 (2009-08-05)
We report the use of 1,3-dithiane combined with aryldiazonium cation for the immobilization of biomolecules based on electrochemical addressing.
Yuncong Chen et al.
Chemical communications (Cambridge, England), 48(42), 5094-5096 (2012-04-20)
A novel sensitive and specific Hg(2+) chemodosimeter, derived from 1',3'-dithiane-substituted 2,1,3-benzoxadiazole, displays "turn-on" fluorescent and colorimetric responses via an Hg(2+)-triggered aldehyde recovery reaction. Its potential to monitor Hg(2+) in living organisms has been demonstrated using zebrafish larvae.
Nasser Iranpoor et al.
The Journal of organic chemistry, 67(9), 2826-2830 (2002-04-27)
A new, mild, and novel method is described for the efficient deoxygenation of sulfoxides to their corresponding sulfides with 1,3-dithiane at room temperature in the presence of catalytic amounts of N-bromosuccinimide (NBS), 2,4,4,6-tetrabromo-2,5-cyclohexadienone (TABCO), or Br(2) as the source of
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