16480
4-溴联苯
technical, ≥90% (GC)
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关于此项目
线性分子式:
C6H5C6H4Br
化学文摘社编号:
分子量:
233.10
EC Number:
202-176-6
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1907453
MDL number:
Assay:
≥90% (GC)
Form:
solid
grade
technical
Quality Level
assay
≥90% (GC)
form
solid
bp
310 °C (lit.)
mp
82-86 °C
solubility
dioxane: soluble 1 g/10 mL, clear, colorless to very faintly yellow
SMILES string
Brc1ccc(cc1)-c2ccccc2
InChI
1S/C12H9Br/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H
InChI key
PKJBWOWQJHHAHG-UHFFFAOYSA-N
General description
In vitro metabolism of 4-bromobiphenyl by cytochrome P-450-dependent monooxygenases in rat hepatic microsomes has been investigated. 4-Bromobiphenyl undergoes reduction to biphenyl in cationic micelles (cetyltrimethyl-ammonium bromide) by electrochemically generated anion radicals of 9-phenylanthracene.
may contain biphenyl and 4,4′-dibromobiphenyl
Application
4-Bromobiphenyl was used in the synthesis of 4-biphenylthiolate.
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
212.0 °F - Not applicable
flash_point_c
100 °C - Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Structure of 4-biphenylthiolate on Au nanoparticle surfaces studied by UV-Vis absorption spectroscopy, transmission electron microscopy and surface-enhanced Raman scattering.
Jang S, et al.
Surface and Interface Analysis : SIA, 36(1), 43-48 (2004)
Electrocatalytic reactions in organized assemblies: Part I. Reduction of 4-bromobiphenyl in cationic and non-ionic micelles.
Rusling JF, et al.
J. Electroanal. Chem. Interfac. Electrochem., 240(1), 201-216 (1988)
A Parkinson et al.
Biochemical pharmacology, 31(10), 1849-1856 (1982-05-15)
The in vitro metabolism of biphenyl, 4-fluoro-, 4-chloro-, 4-bromo- and 4-iodobiphenyl by cytochrome P-450-dependent monooxygenases was investigated using hepatic microsomes from immature male rats pretreated with phenobarbitone or 3-methylcholanthrene. The major route of metabolism of biphenyl and the 4-halobiphenyls was