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文件

195332

1-溴十四烷

Name: 1-溴十四烷
Brand: ALDRICH

97%

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别名:

十四烷基溴, 肉豆蔻基溴

线性分子式:

CH₃(CH₂)₁₃Br

CAS号:

112-71-0

分子量:

277.28

Beilstein:

1742640

EC 号:

203-999-3

MDL编号:

MFCD00000228

PubChem化学物质编号:

24851686

NACRES:

NA.22

检测方案

97%

形式

liquid

折射率

n20/D 1.460 (lit.)

bp

175-178 °C/20 mmHg (lit.)

mp

5-6 °C (lit.)

密度

0.932 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCCCCCBr

InChI

1S/C14H29Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h2-14H2,1H3

InChI key

KOFZTCSTGIWCQG-UHFFFAOYSA-N

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应用

1-溴十四烷可用于合成：

十四烷基二茂铁
阳离子和两性离子双子表面活性剂
基于双[η¹(N)-3,4-二烷氧基亚苄基-4′-十二烷基氧基苯胺]二氯钯 (II) 的带有辛基、癸基、十二烷基、十四烷基和十六烷基烷基的金属配位聚合物
9-十四烷基咔唑

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Experimental and Theoretical Study on Supramolecular Ionic Liquid (IL)-Asphaltene Complex Interactions and Their Effects on the Flow Properties of Heavy Crude Oils.

R Hernández-Bravo et al.

The journal of physical chemistry. B, 122(15), 4325-4335 (2018-03-29)

A combined study for understanding the molecular interactions of asphaltenes with molecular species such as ionic liquids (ILs) comprised experimental measurements and computational numerical simulation calculations, using density-functional theory (DFT) with dispersion corrections, molecular dynamics (MD) calculations, and experimental rheological

Synthesis of N-Tetradecyl-1,10-phenathrolinium-Based New Salts for Biological Applications.

Atakilt Abebe et al.

Bioinorganic chemistry and applications, 2018, 8097483-8097483 (2018-08-18)

New organic salts were synthesized by quaternizing 1,10-phenanthroline using 1-bromotetradecane. The first step yielded an organic salt of formula [C26H37N2]Br. Anion exchange reaction using Li[(CF3SO2)2N] resulted in a more stable salt of formula [C26H37N2][(CF3SO2)2N]. The organic salts were investigated by

Novel Metallomesogenic Polymers Derived from ? 1-Benzylideneaniline Palladium (II) Complex.

Lee M, et al.

Macromolecules, 32(8), 2777-2782 (1999)

Preparation of a Carbazole-Based Macrocycle Via Precipitation-Driven Alkyne Metathesis.

Zhang W, et al.

Organic Syntheses, 177-191 (2007)

Tetradecylferrocene: ordered molecular array of an organometallic amphiphile in the crystal and in a two-dimensional assembled structure on a surface.

Katrin Wedeking et al.

Langmuir : the ACS journal of surfaces and colloids, 22(7), 3161-3165 (2006-03-22)

Tetradecylferrocene (4, Fc-(CH2)13CH3) was synthesized via lithiation of ferrocene by treatment with tert-butyl lithium, followed by alkylation with 1-bromotetradecane. Complex 4 forms a physisorbed ordered molecular monolayer on the surface of highly oriented pyrolytic graphite (HOPG) that was analyzed by

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