19671
4-叔丁基儿茶酚
≥99.0%
别名:
4-(1,1-Dimethylethyl)benzene-1,2-diol, 4-tert-Butylcatechin, 4-tert-Butylpyrocatechol, 4-TBC, p-tert-Butylcatechol
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关于此项目
线性分子式:
(CH3)3CC6H3-1,2-(OH)2
化学文摘社编号:
分子量:
166.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-653-9
Beilstein/REAXYS Number:
2043335
MDL number:
Assay:
≥99.0%
Form:
powder
产品名称
4-叔丁基儿茶酚, ≥99.0%
InChI key
XESZUVZBAMCAEJ-UHFFFAOYSA-N
InChI
1S/C10H14O2/c1-10(2,3)7-4-5-8(11)9(12)6-7/h4-6,11-12H,1-3H3
SMILES string
CC(C)(C)c1ccc(O)c(O)c1
assay
≥99.0%
form
powder
bp
285 °C (lit.)
mp
52-55 °C (lit.)
56-58 °C
solubility
methanol: soluble 1 g/10 mL, clear, colorless
Quality Level
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Application
- 自由基反应的抗氧化剂源：研究发现4-叔丁基儿茶酚可作为活性氢原子源用于自由基反应，特别是脱碘过程。说明它可用于有机合成化学(Povie et al., 2016)。
General description
在酪氨酸酶的催化下，O2 存在下，4- 叔 -丁基邻苯二酚生成 4- 叔 -丁基- O -苯醌 。用循环伏安法和控制电位库仑法研究了 4--叔 -丁基邻苯二酚在 4-羟基香豆素存在下的电化学氧化。它通过阳极氧化进行电化学三聚反应，并利用循环伏安法和控制电位库仑法研究了三聚反应的机理 。
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Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Mechanistic study of electrochemical oxidation of 4-tert-butylcatechol: A facile electrochemical method for the synthesis of new trimer of 4-tert-butylcatechol.
Nematollahi D, et al.
Electrochimica Acta, 49(15), 2495-2502 (2004)
Electrochemical study of 3, 4-dihydroxybenzoic acid and 4-tert-butylcatechol in the presence of 4-hydroxycoumarin application to the electro-organic synthesis of coumestan derivatives.
Golabi SM and Nematollahi D.
Journal of Electroanalytical Chemistry, 430(1), 141-146 (1997)
An unusual delayed patch test reaction to para-tertiary-butylcatechol.
R C Yu et al.
Contact dermatitis, 22(2), 110-111 (1990-02-01)
Martín A Fernández-Baldo et al.
Talanta, 79(3), 681-686 (2009-07-07)
Botrytis cinerea is a plant-pathogenic fungus that produces the disease known as grey mould in a wide variety of agriculturally important hosts in many countries. This paper describes the development of an immunosensor coupled to carbon-based screen-printed electrodes (SPCE) modified
T Kawashima et al.
The Journal of investigative dermatology, 82(1), 53-56 (1984-01-01)
4-Tertiary butyl catechol (TBC) causes depigmentation in humans and animals and stimulates formation of pheomelanosomes. In this study, we investigated the effects of noncytotoxic doses of TBC on glutathione S-transferase (GST) activity in the skin of Uscd strain mice and
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