19671
4-叔丁基儿茶酚
≥99.0%
别名:
4-(1,1-Dimethylethyl)benzene-1,2-diol, 4-tert-Butylcatechin, 4-tert-Butylpyrocatechol, 4-TBC, p-tert-Butylcatechol
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关于此项目
线性分子式:
(CH3)3CC6H3-1,2-(OH)2
化学文摘社编号:
分子量:
166.22
Beilstein:
2043335
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
≥99.0%
表单
powder
沸点
285 °C (lit.)
mp
52-55 °C (lit.)
56-58 °C
溶解性
methanol: soluble 1 g/10 mL, clear, colorless
SMILES字符串
CC(C)(C)c1ccc(O)c(O)c1
InChI
1S/C10H14O2/c1-10(2,3)7-4-5-8(11)9(12)6-7/h4-6,11-12H,1-3H3
InChI key
XESZUVZBAMCAEJ-UHFFFAOYSA-N
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一般描述
在酪氨酸酶的催化下，O2 存在下，4- 叔 -丁基邻苯二酚生成 4- 叔 -丁基- O -苯醌 。用循环伏安法和控制电位库仑法研究了 4--叔 -丁基邻苯二酚在 4-羟基香豆素存在下的电化学氧化。它通过阳极氧化进行电化学三聚反应，并利用循环伏安法和控制电位库仑法研究了三聚反应的机理 。
应用
- 自由基反应的抗氧化剂源：研究发现4-叔丁基儿茶酚可作为活性氢原子源用于自由基反应，特别是脱碘过程。说明它可用于有机合成化学(Povie et al., 2016)。
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Electrochemical study of 3, 4-dihydroxybenzoic acid and 4-tert-butylcatechol in the presence of 4-hydroxycoumarin application to the electro-organic synthesis of coumestan derivatives.
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Journal of Electroanalytical Chemistry, 430(1), 141-146 (1997)
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