197602
奎宁环
97%
别名:
1-氮杂双环[2.2.2]辛烷, ABCO
蒸汽压
1.5 mmHg ( 20 °C)
质量水平
方案
97%
表单
solid
mp
157-160 °C (lit.)
溶解性
H2O: very slightly soluble
H2O: very soluble
alcohol: miscible
diethyl ether: miscible
organic solvents: very soluble
SMILES字符串
C1CN2CCC1CC2
InChI
1S/C7H13N/c1-4-8-5-2-7(1)3-6-8/h7H,1-6H2
InChI key
SBYHFKPVCBCYGV-UHFFFAOYSA-N
基因信息
rat ... Chrm1(25229)
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一般描述
奎宁环是一种双环三级胺，具有桥头氮原子结构，常用于合成碘鎓复合物，并用作光诱导反应的氢原子转移(HAT)催化剂。
应用
奎宁环可用作以下反应的催化剂：
- 醛与丙烯酸甲酯的贝里斯-希尔曼反应。
- α-甲基葡萄糖转化为α-甲基阿洛糖的差向异构化反应。
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
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