211249
三氯化硼 溶液
1.0 M in hexanes
别名:
Boron chloride, Trichloroborane
登录查看公司和协议定价
选择尺寸
关于此项目
经验公式（希尔记法）:
BCl3
化学文摘社编号:
分子量:
117.17
MDL编号:
UNSPSC代码:
12352106
PubChem化学物质编号:
NACRES:
NA.22
蒸汽压
16.13 psi ( 55 °C)
5.22 psi ( 20 °C)
表单
liquid
反应适用性
core: boron
reagent type: catalyst
浓度
1.0 M in hexanes
密度
0.738 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
ClB(Cl)Cl
InChI
1S/BCl3/c2-1(3)4
InChI key
FAQYAMRNWDIXMY-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
一般描述
三氯化硼(BCl3)是常用于切断各类醚C-O键的有机合成试剂。
应用
BCl3可用作：
- 作为试剂与芳基醛合成二氯芳基甲烷（偕二氯化物）。
- 用作路易斯酸，在路易斯碱存在下通过醛和α,β-不饱和酮的贝里斯-希尔曼反应制备syn氯化产物。,·
- 用作催化剂，通过1-三甲基锗基-1-炔烃、二氯硼烷—二甲硫和1,3-丙二醇的硼氢化反应制备(Z)-2-(1-三甲基锗基-1-炔基)-1,3,2-二氧硼烷。
用于制备脂肪酸甲酯以及用于三酸甘油酯的酯交换反应。
警示用语：
Danger
危险分类
Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3
靶器官
Central nervous system, Nervous system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
1.4 °F - closed cup
闪点(°C)
-17 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
A novel synthesis of (Z)-2-(1-trimethylgermyl-1-alkenyl)-1, 3, 2-dioxaborinanes and their conversion into carboxylic acids
Bhat NG, et al.
Tetrahedron Letters, 46(31), 5109-5111 (2005)
Titanium (IV) chloride, zirconium (IV) chloride or boron trichloride and phosphine-promoted Baylis-Hillman reaction of aldehydes with α , β -unsaturated ketone
Shi M, et al.
Journal of the Chemical Society. Perkin Transactions 1, (4), 390-393 (2001)
Conversion of aromatic aldehydes to gem-dichlorides using boron trichloride. A new highly efficient method for preparing dichloroarylmethanes.
Kabalka G W and Wu Z
Tetrahedron Letters, 41(5), 579-581 (2000)
Coördination compounds of boron trichloride; systems with methyl chloride and ethyl chloride.
D R MARTIN et al.
The Journal of physical chemistry, 50(5), 422-427 (1946-09-01)
George W Kabalka et al.
The Journal of organic chemistry, 73(7), 2668-2673 (2008-03-06)
A boron trihalide mediated alkyne-aldehyde coupling reaction leading to stereodefined 1,3,5-triaryl-1,5-dihalo-1,4-pentadienes is described. The study led to the discovery of a direct substitution of hydroxyl groups by stereodefined alkenyl moieties using alkenylboron dihalides. During the investigation, it was also discovered
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持