217964
四丁基四氟硼酸铵
99%, powder
别名:
Ammonium tetra-n-butyl tetrafluoroborate
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关于此项目
线性分子式:
(CH3CH2CH2CH2)4N(BF4)
化学文摘社编号:
分子量:
329.27
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
EC Number:
207-058-8
MDL number:
Beilstein/REAXYS Number:
3577508
产品名称
四丁基四氟硼酸铵, 99%
InChI key
NNZZSJSQYOFZAM-UHFFFAOYSA-N
InChI
1S/C16H36N.BF4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;/q+1;-1
SMILES string
F[B-](F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC
assay
99%
form
powder
mp
155-161 °C (lit.)
solubility
methanol: soluble 10%, clear, colorless
Quality Level
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Application
四丁基四氟硼酸铵可用于以下研究：
- 作为伏安法测定Δ(9)-四氢大麻酚(Δ(9)-THC)的支持电解质。
- 合成生物相关的大环内酯Sansalvamide A。
- 作为循环伏安法测定5,10,15,20-四[3-(3-三氟甲基)苯氧基]卟啉的氧化和还原电位的支持电解质。
- 与1,10-菲咯啉制备1:1加合物。
- 用于在水溶液中制备其他四丁基铵盐。
- 作为合成导电性聚(噻吩)的电解质添加剂。
General description
四氟硼酸四丁基铵被用作合成一系列芳基酮的电解质。
四丁基四氟硼酸铵（TBATFB）是相转移催化剂。它可以通过30％四氟硼酸水溶液与40％氢氧化四丁基铵水溶液反应合成。四丁基四氟硼酸铵可充当电解质，抑制烷基硫代硫酸盐在金上自组装。
四丁基四氟硼酸铵（TBATFB）是相转移催化剂。它可以通过30％四氟硼酸水溶液与40％氢氧化四丁基铵水溶液反应合成。四丁基四氟硼酸铵可充当电解质，抑制烷基硫代硫酸盐在金上自组装。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
No data available
flash_point_c
No data available
ppe
dust mask type N95 (US), Eyeshields, Gloves
Electropolymerization of thiophene with and without aniline in acetonitrile.
Can M, et al.
Turkish Journal of Chemistry, 22, 47-54 (1998)
An efficient electrochemical oxidation of C (sp3)-H bond for the synthesis of arylketones
kong, et al.
Molecular Catalysis, 530, 112633-112633 (2022)
N-Alkylation of imides using phase transfer catalysts under solvent-free conditions
Jakowska, et al.
Journal of Heterocyclic Chemistry, 45, 1371-1375 (2008)
N-Alkylation of imides using phase transfer catalysts under solvent-free conditions.
Jaskowska J and Kowalski P.
Journal of Heterocyclic Chemistry, 45(5), 1371-1375 (2008)
José Antonio Morales-Serna et al.
Organic & biomolecular chemistry, 8(21), 4940-4948 (2010-09-08)
A facile and mild macrolactonization reaction of ω-hydroxy acids was developed based on the transesterification of benzotriazole esters. Treatment of ω-hydroxy acids with 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC) and 1-hydroxy benzotriazole (HOBT) in chloroform provided macrolactones in excellent yields. The reactions were
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