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Merck
CN

230200

硼氢化锂 溶液

greener alternative

2.0 M in THF

别名:

Lithium boron hydride, Lithium hydroborate

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关于此项目

线性分子式:
LiBH4
化学文摘社编号:
分子量:
21.78
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
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form

liquid

Quality Level

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

2.0 M in THF

density

0.896 g/mL at 25 °C

greener alternative category

SMILES string

[Li+].[H][B-]([H])([H])[H]

InChI

1S/BH4.Li/h1H4;/q-1;+1

InChI key

UUKMSDRCXNLYOO-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Lithium borohydride solution is a promising material in greener energy technologies, particularly for hydrogen storage. With a high theoretical hydrogen capacity, it enables compact and efficient energy storage systems that support clean hydrogen-powered applications Click here for more information.

Application

硼氢化锂溶液 (2M in THF) 分别用于 5-亚苄基-2,4-噻唑烷二酮类和 5-亚苄基-4-氧代-2-噻唑烷二酮类的还原,并分别生成 5-苄基-2,4-噻唑烷二酮类和 5-苄基-4-氧代-2-噻唑烷二酮类。
反应物用于:
  • 镓、铟、铼和锌三(巯基咪唑基)氢硼酸配合物的制备
  • 机械化学复分解反应
  • 非催化水解制氢
  • 大型金单层保护簇的生长
  • 阴离子取代反应
  • 脱氢反应

Packaging

推荐将25毫升安全/密封瓶作为一次性使用的瓶子。重复穿刺可能会导致产品性能下降。

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC


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signalword

Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 2

flash_point_f

-0.4 °F - closed cup

flash_point_c

-18 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1

法规信息

监管及禁止进口产品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Regiospecific reduction of 5-benzylidene-2, 4-thiazolidinediones and 4-oxo-2-thiazolidinethiones using lithium borohydride in pyridine and tetrahydrofuran.
Giles RG
Tetrahedron, 56(26), 4531-4537 (2000)
Sumalee Supothina et al.
The Journal of antibiotics, 57(11), 732-738 (2005-02-17)
Optimal fermentation conditions for enniatin production using the entomopathogenic fungus Verticillium hemipterigenum BCC 1449 have been investigated. Among various liquid media tested, highest efficiency of enniatin production was achieved by fermentation in yeast extract sucrose. Application of this condition to
Hui Wu et al.
Nanotechnology, 20(20), 204002-204002 (2009-05-08)
The use of Li3BN2H8 complex hydride as a practical hydrogen storage material is limited by its high desorption temperature and poor reversibility. While certain catalysts have been shown to decrease the dehydrogenation temperature, no significant improvement in reversibility has been



全球贸易项目编号

货号GTIN
230200-2L04061838118677
230200-4X25ML04061838782465
230200-100ML04061838782458
230200-800ML04061838125781