方案
99%
表单
liquid
折射率
n20/D 1.4611 (lit.)
沸点
198-200 °C (lit.)
密度
1.235 g/mL at 25 °C (lit.)
官能团
fluoro
ketone
SMILES字符串
CC(=O)c1cccc(c1)C(F)(F)F
InChI
1S/C9H7F3O/c1-6(13)7-3-2-4-8(5-7)9(10,11)12/h2-5H,1H3
InChI key
ABXGMGUHGLQMAW-UHFFFAOYSA-N
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一般描述
Asymmetric catalytic addition of ethyl groups to 3′-(trifluoromethyl)acetophenone catalyzed by ligands derived from trans-1,2-diaminocyclohexane and camphor sulfonyl chloride has been reported. Phenylation of 3′-(trifluoromethyl)acetophenone in the presence of dihydroxy bis(sulfonamide) ligand (enantioselective catalyst), titanium tetraisopropoxide and diphenylzinc has been investigated.
应用
3′-(Trifluoromethyl)acetophenone has been used in a key step during the preparation of a commercial fungicide.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 1
闪点(°F)
174.2 °F - closed cup
闪点(°C)
79 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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