表单
solid
反应适用性
reagent type: reductant
折射率
n20/D 1.632 (lit.)
沸点
163-165 °C/0.3 mmHg (lit.)
mp
28 °C (lit.)
密度
1.374 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
c1ccc(cc1)[SnH](c2ccccc2)c3ccccc3
InChI
1S/3C6H5.Sn.H/c3*1-2-4-6-5-3-1;;/h3*1-5H;;
InChI key
NFHRNKANAAGQOH-UHFFFAOYSA-N
应用
氢化三苯基锡可作为还原剂用于:
它也可以在9-硼二环[3.3.1]壬烷(9-BBN)作为引发剂的存在下用作自由基还原反应中的自由基前体。
- 在催化量的AIBN存在下的还原性去硒烯化反应。。
- 烯烃的自由基氢锡化。
- α,β-不饱和酮和酯的还原。
它也可以在9-硼二环[3.3.1]壬烷(9-BBN)作为引发剂的存在下用作自由基还原反应中的自由基前体。
警示用语:
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Synthesis of enantiomerically pure perhydrofurob [3, 4-b] pyrans and perhydrofuro [3, 4-b] furans
Tiecco M, et al.
Tetrahedron Asymmetry, 15(12), 1949-1955 (2004)
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Journal of hazardous materials, 192(3), 1860-1868 (2011-08-09)
Triphenyltin (TPT) has high binding affinity with the retinoid X receptor (RXR) in animals. The natural ligand of RXR, 9-cis-retinoic acid (RA), is known to induce featured malformations in vertebrate embryos by disrupting RA signal. Limited information is available on
Jun Xu et al.
Ecotoxicology (London, England), 20(1), 73-80 (2010-10-29)
The toxicity of organotin compounds in the environment is closely related to their uptake by microorganisms and delivery through the food chain. The population at low trophic levels like microalgae plays an important role in this aspect. In this study
Li-Lian Liu et al.
Marine pollution bulletin, 63(5-12), 535-540 (2011-03-08)
The present study was undertaken to evaluate the distribution and accumulation of tributyltin (TBT) and triphenyltin (TPhT) in seawater, sediments and selected organisms from a cage mariculture area in southern Taiwan, Hsiao Liouchiou Island. Our results show that ΣOTs were
Vaso Dokorou et al.
Journal of inorganic biochemistry, 105(2), 195-201 (2011-01-05)
The novel triphenyltin(IV) esters of flufenamic acid (1), Hflu, [Ph(3)Sn(flu)] (2), and of [2-(2,3-dichlorophenylamino)benzoic acid] (3), Hdcpa, [Ph(3)Sn(dcpa)] (4) have been structurally characterized by means of vibrational and (1)H, (13)C NMR spectroscopic studies. The crystal and molecular structures of [SnPh(3)(dcpa)(DMSO)]
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