249955
氯化锡(IV) 溶液
1.0 M in methylene chloride
别名:
四氯化锡, 氯化高锡
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关于此项目
线性分子式:
SnCl4
化学文摘社编号:
分子量:
260.52
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352106
MDL number:
产品名称
氯化锡(IV) 溶液, 1.0 M in methylene chloride
InChI
1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
SMILES string
Cl[Sn](Cl)(Cl)Cl
InChI key
HPGGPRDJHPYFRM-UHFFFAOYSA-J
form
liquid
reaction suitability
core: tin
reagent type: catalyst
concentration
1.0 M in methylene chloride
density
1.419 g/mL at 25 °C
Quality Level
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Application
氯化锡（IV）溶液可用于聚砜的氯甲基化反应，以开发聚合物电解质膜。
General description
氯化锡（IV）具有路易斯酸的特征，并通常通过溶胶-凝胶法用于合成SnO2纳米颗粒。
Packaging
推荐将25毫升安全/密封™瓶作为一次性使用的瓶子。重复穿刺可能会导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Molecular addition compounds of tin (IV) chloride. I. Interaction with benzonitriles in benzene solution.
Brown TL and Kubota M
Journal of the American Chemical Society, 83(2), 331-334 (1961)
Solid-State and Solution Structural Study of Acetylacetone-Modified Tin (IV) Chloride Used as a Precursor of SnO2 Nanoparticles Prepared by a Sol- Gel Route.
Briois V, et al.
Chemistry of Materials, 16(20), 3885-3894 (2004)
Phosphoric acid doped polysulfone membranes with aminopyridine pendant groups and imidazole cross-links.
Hink S, et al.
European Polymer Journal, 72(20), 102-113 (2015)
Gerry A Griffith et al.
Journal of the American Chemical Society, 128(40), 13130-13141 (2006-10-05)
Difluorinated alkenoate ethyl 3,3-difluoro-2-(N,N-diethylcarbamoyloxy)-2-propenoate reacts rapidly and in high yield with furan and a range of substituted furans in the presence of a tin(IV) catalyst. Non-fluorinated congener 2-(N,N-diethylcarbamoyloxy)-2-propenoate fails to react at all under the same conditions. These reactions have
Yasuyuki Kita et al.
The Journal of organic chemistry, 71(14), 5191-5197 (2006-07-01)
The Lewis acid-promoted rearrangement of 2,2,3,3-tetrasubstituted 2,3-epoxy alcohols with several kinds of protecting groups was investigated. When SnCl4 is used as a Lewis acid, the reaction proceeds in a regio- and stereo-controlled manner to afford two types of carbonyl compounds
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