警示用语：
Danger
危险分类
Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
4.1B - Flammable solid hazardous materials
WGK
nwg
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Isolda Romero-Canelón et al.
Journal of medicinal chemistry, 56(3), 1291-1300 (2013-02-02)
Organometallic half-sandwich complexes [M(p-cymene)(azo/imino-pyridine)X](+) where M = Ru(II) or Os(II) and X ═ Cl or I, exhibit potent antiproliferative activity toward a range of cancer cells. Not only are the iodido complexes more potent than the chlorido analogues, but they
Kilian Muñiz
Chemical Society reviews, 33(3), 166-174 (2004-03-18)
Imido complexes of osmium tetroxide are versatile compounds for olefin functionalisation. This tutorial review offers a brief historical overview on these compounds and discusses the electronic properties and reactivities of isolated imido osmium compounds in what had been the original
Bastien Boff et al.
Inorganic chemistry, 52(5), 2705-2715 (2013-02-23)
A library of 29 organoosmium compounds has been built up with known and novel cyclometalated compounds obtained with C-N, N(∧)C(∧)N, and C(∧)N(∧)N ligands. All compounds have been tested for their in vitro cytotoxic properties against A172, a tumor cell line
Hideki Sugimoto et al.
Inorganic chemistry, 52(2), 543-545 (2013-01-01)
Oxidation of the hydroxoosmium(III) complex resulted in C-H bond activation of the methyl group of the supporting ligand (N,N'-dimethyl-2,11-diaza[3.3](2,6)pyridinophane). The product was an osmium(IV) complex exhibiting a seven-coordinate structure with an additional Os-CH(2) bond.
Carole J R Bataille et al.
Chemical Society reviews, 40(1), 114-128 (2010-11-05)
Numerous synthetic protocols for producing syn-diols from the corresponding alkenes have been developed and published over recent years. It is the intent of the following tutorial review to present a concise summary of the main methods used to prepare syn-diol
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