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275034

9,10-菲醌

Name: 9,10-菲醌
Brand: ALDRICH

95%

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别名:

9,10-菲二酮

经验公式（希尔记法）:

C₁₄H₈O₂

CAS号:

84-11-7

分子量:

208.21

Beilstein:

608838

EC 号:

201-515-5

MDL编号:

MFCD00001163

PubChem化学物质编号:

24856622

NACRES:

NA.23

检测方案

95%

形式

powder

mp

209-212 °C (lit.)

SMILES string

O=C1C(=O)c2ccccc2-c3ccccc13

InChI

1S/C14H8O2/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(13)16/h1-8H

InChI key

YYVYAPXYZVYDHN-UHFFFAOYSA-N

Gene Information

human ... PTPN1(5770) , PTPRC(5788)

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一般描述

多环芳烃的醌类在所有燃烧的有机物质中含量丰富。在用于钝化硅表面时，它通过杂原子 Diels-Alder 反应与表面上的悬挂键发生反应。因为 π-电子共轭，硅的半导体性质不受影响。

应用

9,10-菲醌可用于在硅 (100) 表面进行高质量钝化。醌类可作为多种黄酶的底物。

象形图

GHS07,GHS09

警示用语：

Warning

危险声明

H319 - H400

预防措施声明

P264 - P273 - P280 - P305 + P351 + P338 - P337 + P313 - P391

危险分类

Aquatic Acute 1 - Eye Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

473.0 °F

闪点(°C)

245 °C

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

分析证书(COA)

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示例

T1503

货号

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包装规格/数量

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705578-5MG-PW

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Mutagenicity of quinones: pathways of metabolic activation and detoxification.

P L Chesis et al.

Proceedings of the National Academy of Sciences of the United States of America, 81(6), 1696-1700 (1984-03-01)

The mutagenicity of various quinones, a class of compounds widely distributed in nature, is demonstrated in the Salmonella TA104 tester strain. The metabolic pathways by which four quinones, menadione, benzo[a]pyrene 3,6-quinone, 9,10-phenanthrenequinone, and danthron, caused mutagenicity in this test system

Electronic structure and band alignment of 9, 10-phenanthrenequinone passivated silicon surfaces

Avasthi, Sushobhan, et al.

Surface Science, 605(13), 1308-1312 (2011)

Redox cycling of 9,10-phenanthraquinone to cause oxidative stress is terminated through its monoglucuronide conjugation in human pulmonary epithelial A549 cells.

Keiko Taguchi et al.

Free radical biology & medicine, 44(8), 1645-1655 (2008-02-26)

9,10-Phenanthraquinone (PQ), a component of airborne particulate matter, causes marked cellular protein oxidation and cytotoxicity through a two-electron reduction to 9,10-dihydroxyphenanthrene (PQH2), which is associated with the propagation of reactive oxygen species (K. Taguchi et al., Free Radic. Biol. Med.

9,10-Phenanthrenequinone induces DNA deletions and forward mutations via oxidative mechanisms in the yeast Saccharomyces cerevisiae.

Chester E Rodriguez et al.

Toxicology in vitro : an international journal published in association with BIBRA, 22(2), 296-300 (2007-10-26)

The estimated cancer risk from diesel exhaust particles (DEP) in the air is approximately 70% of the cancer risk from all air pollutants. DEP is comprised of a complex mixture of chemicals whose carcinogenic potential has not been adequately assessed.

An indomethacin analogue, N-(4-chlorobenzoyl)-melatonin, is a selective inhibitor of aldo-keto reductase 1C3 (type 2 3alpha-HSD, type 5 17beta-HSD, and prostaglandin F synthase), a potential target for the treatment of hormone dependent and hormone independent malignancies.

Michael C Byrns et al.

Biochemical pharmacology, 75(2), 484-493 (2007-10-24)

Aldo-keto reductase (AKR) 1C3 (type 2 3alpha-HSD, type 5 17beta-HSD, and prostaglandin F synthase) regulates ligand access to steroid hormone and prostaglandin receptors and may stimulate proliferation of prostate and breast cancer cells. NSAIDs are known inhibitors of AKR1C enzymes.

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