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Merck
CN

275034

9,10-菲醌

95%

别名:

9,10-菲二酮

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关于此项目

经验公式(希尔记法):
C14H8O2
化学文摘社编号:
分子量:
208.21
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
201-515-5
Beilstein/REAXYS Number:
608838
MDL number:
Assay:
95%
Form:
powder
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InChI key

YYVYAPXYZVYDHN-UHFFFAOYSA-N

InChI

1S/C14H8O2/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(13)16/h1-8H

SMILES string

O=C1C(=O)c2ccccc2-c3ccccc13

assay

95%

form

powder

Quality Level

Gene Information

mp

209-212 °C (lit.)

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General description

多环芳烃的醌类在所有燃烧的有机物质中含量丰富。在用于钝化硅表面时,它通过杂原子 Diels-Alder 反应与表面上的悬挂键发生反应。因为 π-电子共轭,硅的半导体性质不受影响。

Application

9,10-菲醌可用于在硅 (100) 表面进行高质量钝化。醌类可作为多种黄酶的底物。

pictograms

Exclamation markEnvironment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Eye Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

473.0 °F

flash_point_c

245 °C

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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P L Chesis et al.
Proceedings of the National Academy of Sciences of the United States of America, 81(6), 1696-1700 (1984-03-01)
The mutagenicity of various quinones, a class of compounds widely distributed in nature, is demonstrated in the Salmonella TA104 tester strain. The metabolic pathways by which four quinones, menadione, benzo[a]pyrene 3,6-quinone, 9,10-phenanthrenequinone, and danthron, caused mutagenicity in this test system
Electronic structure and band alignment of 9, 10-phenanthrenequinone passivated silicon surfaces
Avasthi, Sushobhan, et al.
Surface Science, 605(13), 1308-1312 (2011)
Keiko Taguchi et al.
Free radical biology & medicine, 44(8), 1645-1655 (2008-02-26)
9,10-Phenanthraquinone (PQ), a component of airborne particulate matter, causes marked cellular protein oxidation and cytotoxicity through a two-electron reduction to 9,10-dihydroxyphenanthrene (PQH2), which is associated with the propagation of reactive oxygen species (K. Taguchi et al., Free Radic. Biol. Med.
Chester E Rodriguez et al.
Toxicology in vitro : an international journal published in association with BIBRA, 22(2), 296-300 (2007-10-26)
The estimated cancer risk from diesel exhaust particles (DEP) in the air is approximately 70% of the cancer risk from all air pollutants. DEP is comprised of a complex mixture of chemicals whose carcinogenic potential has not been adequately assessed.
Naoya Kishikawa et al.
Talanta, 85(1), 809-812 (2011-06-08)
9,10-Phenanthrenequinone (PQ) is harmful environmental pollutant that is detected in airborne particulates. The measurement of PQ in the air should be necessary to evaluate the potential adverse effects of PQ on human health. We have recently developed a determination method

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