282367
(1S,2S,3R,5S)-(+)-蒎烷二醇
99%
别名:
(+)-2-羟基异松蒎醇, (1S,2S,3R,5S)-2,3-蒎烷二醇, (1S,2S,3R,5S)-2,6,6-三甲基二环[3.1.1]庚-2,3-二醇, [1S-(1α,2α,3α,5α)]-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇
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关于此项目
经验公式（希尔记法）:
C10H18O2
化学文摘社编号:
分子量:
170.25
Beilstein:
1853591
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
99%
表单
solid
旋光性
[α]20/D +8.5°, c = 6.5 in toluene
光学纯度
ee: 99% (GLC)
mp
57-59 °C (lit.)
官能团
hydroxyl
SMILES字符串
CC1(C)C2C[C@@H](O)[C@@](C)(O)C1C2
InChI
1S/C10H18O2/c1-9(2)6-4-7(9)10(3,12)8(11)5-6/h6-8,11-12H,4-5H2,1-3H3/t6-,7-,8+,10-/m0/s1
InChI key
MOILFCKRQFQVFS-OORONAJNSA-N
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应用
(1S,2S,3R,5S)-(+)-蒎烷二醇可用作手性试剂，用于合成α-羟基酮 和脯氨酸硼酸酯的拆分。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Selective oxidation of optically active sec,sec-1,2-diols by dioxiranes. A practical method for the synthesis of homochiral .alpha.-hydroxy ketones in high optical purity
Lucia D'Accolti, et al.
The Journal of Organic Chemistry, 58, 14, 3600-3601 (1993)
The efficient synthesis and simple resolution of a prolineboronate ester suitable for enzyme-inhibition studies
Terence A.K, et al.
Tetrahedron, 49, 5, 1009-1016 (1993)
Ricardo Lira et al.
Organic letters, 9(21), 4315-4318 (2007-09-18)
syn-beta-Hydroxyallylsilanes of general structure 11 and 28 are prepared in 50-86% yield and 91-95% ee (for aliphatic aldehydes; 50% ee for benzaldehyde) via the BF(3).Et(2)O-promoted gamma-silylallylboration reactions, using reagents 14 and 15.
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