303461
(R)-(+)-β-香茅醇
95%
别名:
(+)-β-香茅醇, (R)-3,7-二甲基-6-辛烯-1-醇
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关于此项目
线性分子式:
(CH3)2C=CHCH2CH2CH(CH3)CH2CH2OH
化学文摘社编号:
分子量:
156.27
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-250-5
Beilstein/REAXYS Number:
1721506
MDL number:
产品名称
(R)-(+)-β-香茅醇, 95%
InChI key
QMVPMAAFGQKVCJ-SNVBAGLBSA-N
InChI
1S/C10H20O/c1-9(2)5-4-6-10(3)7-8-11/h5,10-11H,4,6-8H2,1-3H3/t10-/m1/s1
SMILES string
C[C@@H](CCO)CC\C=C(\C)C
vapor pressure
~0.02 mmHg ( 25 °C)
assay
95%
form
liquid
optical activity
[α]19/D +5.3°, neat
refractive index
n20/D 1.456 (lit.)
bp
112-113 °C/12 mmHg (lit.)
density
0.857 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
Application
(R)-(+)-β-香茅醇可用于制备：
它也可用作合成α-乙酰氨基肉桂酸的原料。
- (R)-(+)-β-香茅醇乙酸酯，以固定化米黑根毛霉脂肪酶为生物催化剂通过乙酸乙烯酯的酯交换反应制备。
- (R)-(+)-香茅醛和 (R)-(+)-香茅酸，通过氧化反应制备。
- 香茅醇氮丙啶， 通过2,2,2-三氯乙氧基磺酰胺的分子间烯烃叠氮化作用制备。
它也可用作合成α-乙酰氨基肉桂酸的原料。
(R)-(+)-β-香茅醛可以进行：
- 氧化形成 (R)-(+)-香茅醛（一种 抗真菌剂)和 (R)-(+)-香茅酸。
- 与2,2,2-三氯乙氧基磺酰胺进行分子间烯烃叠氮反应，形成可用于开环反应的香茅醇氮丙啶。
- 一系列反应以形成治疗广泛性焦虑症和失眠用α2δ-配体。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
212.0 °F - closed cup
flash_point_c
100 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Abir B Majumder et al.
Chemistry Central journal, 1, 10-10 (2007-09-21)
Use of enzymes in low water media is now widely used for synthesis and kinetic resolution of organic compounds. The frequently used enzyme form is the freeze-dried powders. It has been shown earlier that removal of water molecules from enzyme
Rh-catalyzed alkene oxidation: a highly efficient and selective process for preparing N-alkoxysulfonyl aziridines.
Guthikonda K, et al.
Tetrahedron, 62(49), 11331-11342 (2006)
A novel synthesis of (+)-integerrinecic acid lactone from R-(+) β-citronellol
White JD and Jayasinghe LR
Tetrahedron Letters, 29(18), 2139-2142 (1988)
Phenylglycine methyl ester, a useful tool for absolute configuration determination of various chiral carboxylic acids.
Yabuuchi T and Kusumi T
The Journal of Organic Chemistry, 65(2), 397-404 (2000)
Diastereoselective, large-scale synthesis of ?-amino acids via asymmetric aza-Michael addition as ?2? ligands for the treatment of generalized anxiety disorder and insomnia.
Magano J, et al.
Tetrahedron Letters, 50(46), 6325-6328 (2009)
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