方案
97%
表单
liquid
折射率
n20/D 1.436 (lit.)
沸点
83 °C (lit.)
密度
0.991 g/mL at 25 °C (lit.)
官能团
chloro
储存温度
2-8°C
SMILES字符串
ClC1CCC1
InChI
1S/C4H7Cl/c5-4-2-1-3-4/h4H,1-3H2
InChI key
STJYMUBZVMSMBP-UHFFFAOYSA-N
一般描述
Cyclobutyl chloride is formed by rearrangements concerted with fragmentation of cyclopropylmethoxychlorocarbene and cyclobutoxychlorocarbene. The thermal decomposition of cyclobutyl chloride was investigated over the temperature range of 892-1150K using very low-pressure pyrolysis technique.
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
15.8 °F - closed cup
闪点(°C)
-9 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Robert A Moss et al.
Journal of the American Chemical Society, 126(27), 8466-8476 (2004-07-09)
Fragmentations of cyclopropylmethoxychlorocarbene (6) and cyclobutoxychlorocarbene (10) lead to rearrangments that afford mixtures of cyclopropylmethyl chloride (7), cyclobutyl chloride (8), and 3-butenyl chloride (9). Isotopic substitution studies show that these rearrangments are accompanied by partial exchange of the methylene groups
Competitive unimolecular reactions at low pressures. The pyrolysis of cyclobutyl chloride.
King KD, et al.
International Journal of Chemical Kinetics, 11(1), 11-21 (1979)
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