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Merck
CN

333565

环丁基氯

97%

别名:

氯环丁烷

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关于此项目

经验公式(希尔记法):
C4H7Cl
化学文摘社编号:
分子量:
90.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
214-314-2
MDL number:
Assay:
97%
Form:
liquid
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InChI key

STJYMUBZVMSMBP-UHFFFAOYSA-N

InChI

1S/C4H7Cl/c5-4-2-1-3-4/h4H,1-3H2

SMILES string

ClC1CCC1

assay

97%

form

liquid

refractive index

n20/D 1.436 (lit.)

bp

83 °C (lit.)

density

0.991 g/mL at 25 °C (lit.)

functional group

chloro

storage temp.

2-8°C

General description

Cyclobutyl chloride is formed by rearrangements concerted with fragmentation of cyclopropylmethoxychlorocarbene and cyclobutoxychlorocarbene. The thermal decomposition of cyclobutyl chloride was investigated over the temperature range of 892-1150K using very low-pressure pyrolysis technique.

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

15.8 °F - closed cup

flash_point_c

-9 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number

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Robert A Moss et al.
Journal of the American Chemical Society, 126(27), 8466-8476 (2004-07-09)
Fragmentations of cyclopropylmethoxychlorocarbene (6) and cyclobutoxychlorocarbene (10) lead to rearrangments that afford mixtures of cyclopropylmethyl chloride (7), cyclobutyl chloride (8), and 3-butenyl chloride (9). Isotopic substitution studies show that these rearrangments are accompanied by partial exchange of the methylene groups
Competitive unimolecular reactions at low pressures. The pyrolysis of cyclobutyl chloride.
King KD, et al.
International Journal of Chemical Kinetics, 11(1), 11-21 (1979)

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